Photomultiplier tubes (PMTs) are often used in low-background particle physics experiments, which rely on an excellent response to single-photon signals and stable long-term operation. In particular, the Hamamatsu R11410 model is the light sensor of choice for liquid xenon dark matter experiments, including XENONnT. The same PMT model was also used for the predecessor, XENON1T, where issues affecting its long-term operation were observed. Here, we report on an improved PMT testing procedure which ensures optimal performance in XENONnT. Using both new and upgraded facilities, we tested 368 new PMTs in a cryogenic xenon environment. We developed new tests targeted at the detection of light emission and the degradation of the PMT vacuum through small leaks, which can lead to spurious signals known as afterpulses, both of which were observed in XENON1T. We exclude the use of 26 of the 368 tested PMTs and categorise the remainder according to their performance. Given that we have improved the testing procedure, yet we rejected fewer PMTs, we expect significantly better PMT performance in XENONnT.

The selection of low-radioactive construction materials is of utmost importance for the success of lowenergy rare event search experiments. Besides radioactive contaminants in the bulk, the emanation of radioactive radon atoms from material surfaces attains increasing relevance in the effort to further reduce the background of such experiments. In this work, we present the 222Rn emanation measurements performed for the XENON1T dark matter experiment. Together with the bulk impurity screening campaign, the results enabled us to select the radio-purest construction materials, targeting a 222Rn activity concentration of 10 mu Bq/kg in 3.2 t of xenon. The knowledge of the distribution of the 222Rn sources allowed us to selectively eliminate problematic components in the course of the experiment. The predictions from the emanation measurements were compared to data of the 222Rn activity concentration in XENON1T. The final 222Rn activity concentration of (4.5 +/- 0.1) mu Bq/kg in the target of XENON1T is the lowest ever achieved in a xenon dark matter experiment.

We report on a search for nuclear recoil signals from solar B-8 neutrinos elastically scattering off xenon nuclei in XENON1T data, lowering the energy threshold from 2.6 to 1.6 keV. We develop a variety of novel techniques to limit the resulting increase in backgrounds near the threshold. No significant B-8 neutrinolike excess is found in an exposure of 0.6 t x y. For the first time, we use the nondetection of solar neutrinos to constrain the light yield from 1-2 keV nuclear recoils in liquid xenon, as well as nonstandard neutrino-quark interactions. Finally, we improve upon world-leading constraints on dark matter-nucleus interactions for dark matter masses between 3 and 11 GeV c(-2) by as much as an order of magnitude.

We report the results of a search for the inelastic scattering of weakly interacting massive particles (WIMPs) in the XENON1T dark matter experiment. Scattering off Xe-129 is the most sensitive probe of inelastic WIMP interactions, with a signature of a 39.6 keV deexcitation photon detected simultaneously with the nuclear recoil. Using an exposure of 0.83 tonne-years, we find no evidence of inelastic WIMP scattering with a significance of more than 2 sigma. A profile-likelihood ratio analysis is used to set upper limits on the cross section of WIMP-nucleus interactions. We exclude new parameter space for WIMPs heavier than 100 GeV/c(2), with the strongest upper limit of 3.3 x 10(-39) cm(2) for 130 GeV/c(2) WIMPs at 90% confidence level.

Xenon dual-phase time projection chambers designed to search for weakly interacting massive particles have so far shown a relative energy resolutionwhich degrades with energy above similar to 200 keV due to the saturation effects. This has limited their sensitivity in the search for rare events like the neutrinoless double-beta decay of Xe-136 at its Q value, Q(beta beta) similar or equal to 2.46 MeV. For the XENON1T dual-phase time projection chamber, we demonstrate that the relative energy resolution at 1 sigma/mu is as low as (0.80 +/- 0.02)% in its one-ton fiducial mass, and for single-site interactions at Q(beta beta). We also present a new signal correction method to rectify the saturation effects of the signal readout system, resulting in more accurate position reconstruction and indirectly improving the energy resolution. The very good result achieved in XENON1T opens up new windows for the xenon dual-phase dark matter detectors to simultaneously search for other rare events.

Astronomical and cosmological observations on different scales point to the existence of dark matter. In the current cosmological paradigm this dark matter accounts for about 26% of the energy-density of the universe, yet has not been directly observed. Weakly Interacting Massive Particles (WIMPs) and axions are two candidates among the many theories and particles proposed to explain dark matter. Direct detection experiments aim to detect the scattering or coupling of dark matter to the detector medium. The event rate in such experiments is expected to exhibit an annual modulation due to the motion of the Earth through the Galactic dark matter halo. The XENON collaboration built several experiments that have searched for WIMP dark matter by looking for WIMPs scattering on xenon nuclei. The heart of these detectors consists of a Time Projection Chamber (TPC) which records the scintillation light (S1) and ionization charge (S2) signal following a recoiling xenon nucleus as well as its position and time. Using these ultra-low background detectors, the XENON collaboration has set world-leading exclusion limits on the WIMP-nucleon scattering cross-section. In this thesis several different ways of enhancing direct detection experiments are presented, involving time dependent signal models, event reconstruction and a method enhancing statistical inference. First, during a search for event rate modulation, spanning almost 4 years of XENON100 data, no oscillation was found to be compatible with the expected signature. This thesis presents a verification of the correctness of the test statistic distribution used in this analysis using dedicated simulations. Second, the positions of interactions in XENON detectors are used for detector volume fiducialization as well as for modeling the position dependent detector response. This thesis presents the position reconstruction methods used during the first XENON1T science analysis. Third, a new algorithm for position and energy reconstruction using the likelihood-free paradigm is presented. This simulator-based method increases the accuracy of the previous method by up to 15% and can simultaneously infer the transverse position and size of the charge signal. Fourth, to enhance the physics reach of future dark matter searches using xenon TPCs, a new method for computing differential rates is developed. This method replaces the calculation usually performed by Monte-Carlo simulations with an equivalent analytic expression. This enables the use of higher dimensional explicit (profile) likelihood functions, resulting in better signal-background discrimination. The new method uses time dependent signal models (encoding annual modulation) as well as spatially non-uniform sources such as a radiogenic neutron background and fully accounts for the non-uniform detector response. This method can significantly reduce the exposure needed for a potential dark matter discovery in future detectors such as XENONnT. Lastly, the amplitude of the axion dark matter field is expected to exhibit stochastic behavior. Experiments whose measurements are shorter than the coherence time of the field need to include this effect in their data analysis and inference. This thesis presents an analysis of a simulated axion signal in a CASPEr-ZULF-like detector, showing that exclusion limits on the axion amplitude are too strong by a factor ~4 when not including the axion amplitude fluctuation.

We report results from searches for new physics with low-energy electronic recoil data recorded with the XENONIT detector. With an exposure of 0.65 tonne-years and an unprecedentedly low background rate of 76 +/- 2(stat) events/(tonne x year x keV) between 1 and 30 keV, the data enable one of the most sensitive searches for solar axions, an enhanced neutrino magnetic moment using solar neutrinos, and bosonic dark matter. An excess over known backgrounds is observed at low energies and most prominent between 2 and 3 keV. The solar axion model has a 3.4 sigma significance, and a three-dimensional 90% confidence surface is reported for axion couplings to electrons, photons, and nucleons. This surface is inscribed in the cuboid defined by g(ae) < 3.8 x 10(-12), g(ae)g(an)(eff) < 4.8 x 10(-18), and g(ae)g(a gamma) < 7.7 x 10(-22) GeV-1, and excludes either g(ae) = 0 or g(ae)g(a gamma) = g(ae)ge(an)(eff), = 0. The neutrino magnetic moment signal is similarly favored over background at 3.2 sigma, and a confidence interval of mu(nu) is an element of (1.4, 2.9) x 10(-11) mu(B) (90% C.L.) is reported. Both results are in strong tension with stellar constraints. The excess can also be explained by beta decays of tritium at 3.2 sigma significance with a corresponding tritium concentration in xenon of (6.2 +/- 2.0) x 10(-25) mol/mol. Such a trace amount can neither be confirmed nor excluded with current knowledge of its production and reduction mechanisms. The significances of the solar axion and neutrino magnetic moment hypotheses arc decreased to 2.0 sigma and 0.9 sigma, respectively, if an unconstrained tritium component is included in the fitting. With respect to bosonic dark matter, the excess favors a monoenergetic peak at (2.3 +/- 0.2) keV (68% C.L.) with a 3.0 sigma global (4.0 sigma local) significance over background. This analysis sets the most restrictive direct constraints to date on pseudoscalar and vector bosonic dark matter for most masses between 1 and 210 keV/c(2). We also consider the possibility that Ar-37 may be present in the detector, yielding a 2.82 keV peak from electron capture. Contrary to tritium, the Ar-37 concentration can be tightly constrained and is found to be negligible.

Liquid xenon time-projection chambers are the world's most sensitive detectors for a wide range of dark matter candidates. We show that the statistical analysis of their data can be improved by replacing detector response Monte Carlo simulations with an equivalent deterministic calculation. This allows the use of high-dimensional undiscretized models, yielding up to similar to 2 times better discrimination of the dominant backgrounds. In turn, this could significantly extend the physics reach of upcoming experiments such as XENONnT and LZ, and bring forward a potential 5 sigma dark matter discovery by over a year.

XENONnT is a dark matter direct detection experiment, utilizing 5.9 t of instrumented liquid xenon, located at the INFN Laboratori Nazionali del Gran Sasso. In this work, we predict the experimental background and project the sensitivity of XENONnT to the detection of weakly interacting massive particles (WIMPs). The expected average differential background rate in the energy region of interest, corresponding to (1, 13) keV and (4, 50) keV for electronic and nuclear recoils, amounts to 12.3 +/- 0.6 (keV t y)(-1) and (2.2 +/- 0.5) x 10(-3 )(keV t y)(-1), respectively, in a 4t fiducial mass. We compute unified confidence intervals using the profile construction method, in order to ensure proper coverage. With the exposure goal of 20 t y, the expected sensitivity to spin-independent WIMP-nucleon interactions reaches a cross-section of 1.4 x 10(-48) cm(2) for a 50 GeV/c(2) mass WIMP at 90% confidence level, more than one order of magnitude beyond the current best limit, set by XENON1T. In addition, we show that for a 50 GeV/c(2) WIMP with cross-sections above 2.6 x 10(-48) cm(2) (5.0 x 10(-48) cm(2)) the median XENONnT discovery significance exceeds 3 sigma (5 sigma). The expected sensitivity to the spin-dependent WIMP coupling to neutrons (protons) reaches 2.2 x 10(-43) cm(2) (6.0 x 10(-42) cm(2)).

We detail the sensitivity of the proposed liquid xenon DARWIN observatory to solar neutrinos via elastic electron scattering. We find that DARWIN will have the potential to measure the fluxes of five solar neutrino components: pp, 7Be, 13N, 15O and pep. The precision of the 13N, 15O and pep components is hindered by the double-beta decay of 136Xe and, thus, would benefit from a depleted target. A high-statistics observation of pp neutrinos would allow us to infer the values of the electroweak mixing angle, sin2 theta w, and the electron-type neutrino survival probability, Pee, in the electron recoil energy region from a few keV up to 200 keV for the first time, with relative precision of 5% and 4%, respectively, with 10 live years of data and a 30 tonne fiducial volume. An observation of pp and 7Be neutrinos would constrain the neutrino-inferred solar luminosity down to 0.2%. A combination of all flux measurements would distinguish between the high- (GS98) and low-metallicity (AGS09) solar models with 2.1-2.5 sigma significance, independent of external measurements from other experiments or a measurement of 8B neutrinos through coherent elastic neutrino-nucleus scattering in DARWIN. Finally, we demonstrate that with a depleted target DARWIN may be sensitive to the neutrino capture process of 131Xe.