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Selective Alkylation of (Hetero)Aromatic Amines with Alcohols Catalyzed by a Ruthenium Pincer Complex
Stockholm University, Faculty of Science, Department of Organic Chemistry.
Stockholm University, Faculty of Science, Department of Organic Chemistry.
Stockholm University, Faculty of Science, Department of Organic Chemistry.ORCID iD: 0000-0002-7898-317X
2012 (English)In: Organic Letters, ISSN 1523-7060, E-ISSN 1523-7052, Vol. 14, no 6, p. 1456-1459Article in journal (Refereed) Published
Abstract [en]

A readily available pincer ruthenium(II) complex catalyzes the selective monoalkylation of (hetero)aromatic amines with a wide range of primary alcohols (including pyridine-, furan-, and thiophene-substituted alcohols) with high efficiency when used in low catalyst loadings (1 mol %). Tertiary amine formation via polyalkylation does not occur, making this ruthenium system an excellent catalyst for the synthesis of sec-amines.

Place, publisher, year, edition, pages
2012. Vol. 14, no 6, p. 1456-1459
National Category
Chemical Sciences
Identifiers
URN: urn:nbn:se:su:diva-76125DOI: 10.1021/ol3001969ISI: 000301516000025OAI: oai:DiVA.org:su-76125DiVA, id: diva2:526173
Funder
Swedish Research Council
Note

3

Available from: 2012-05-10 Created: 2012-05-09 Last updated: 2018-04-06Bibliographically approved

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Agrawal, SantoshMartín-Matute, Belén
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