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Olefin-Directed Palladium-Catalyzed Regio- and Stereoselective Hydroboration of Allenes
Stockholm University, Faculty of Science, Department of Organic Chemistry.ORCID iD: 0000-0001-6604-6173
Stockholm University, Faculty of Science, Department of Organic Chemistry.
Stockholm University, Faculty of Science, Department of Organic Chemistry.
Stockholm University, Faculty of Science, Department of Organic Chemistry.
2016 (English)In: Chemistry - A European Journal, ISSN 0947-6539, E-ISSN 1521-3765, Vol. 22, no 9, p. 2939-2943Article in journal (Refereed) Published
Abstract [en]

An olefin-directed palladium-catalyzed regio- and stereoselective hydroboration of allenes has been developed to afford fully substituted alkenylboron compounds. The reaction showed a broad substrate scope: a number of functionalized allenes, including 2,3-dienoate, 3,4-dienoate, 3,4-dienol, 1,2-allenylphosphonate, and alkyl-substituted allenes, could be used in this olefin-directed allene hydroboration. The olefin unit was proven to be an indispensable element for this transformation.

Place, publisher, year, edition, pages
Wiley-VCH Verlagsgesellschaft, 2016. Vol. 22, no 9, p. 2939-2943
Keywords [en]
allenes, directing group, hydroboration, olefin, palladium
National Category
Organic Chemistry
Identifiers
URN: urn:nbn:se:su:diva-127917DOI: 10.1002/chem.201505130ISI: 000370452300015PubMedID: 26710968OAI: oai:DiVA.org:su-127917DiVA, id: diva2:911740
Funder
EU, European Research CouncilSwedish Research CouncilBerzelii Centre EXSELENTKnut and Alice Wallenberg FoundationAvailable from: 2016-03-14 Created: 2016-03-14 Last updated: 2020-03-05Bibliographically approved

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