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Synthesis of some oligosaccharides with D-galacto- and D-gluco-configuration and reductive opening of carbo-hydrate acetals
Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för organisk kemi.
1985 (engelsk)Doktoravhandling, med artikler (Annet vitenskapelig)
Abstract [en]

Syntheses of the following oligosaccharides, required for immunological studies. are discussed: £-trifluoroacetamidophenyl O-a-D-glucopyranosyl-(1+4)-a-D-galactopyranoside, ß-trifluoroacetamidophenyl O-a-D-glucopyranosyl-(1 + 6)-a-D-galactopyranoside, 8-methoxy- carbonyloct-1-yl 0-a-D-galactopyranosyl-(1+3)-fi-ß~9"9alact°Pyranosyl- (1+4)-2-acetamido-2-deoxy-ß-D-glucopyranoside, methyl û-a-D-fuco- pyranosyl-(1+4)-ß-D-galactopyranoside, methyl û-a-D-galactopyranosyl- (1+4)-ß-D-fucopyranoside and methyl ß-a-D-fucopyranosyl-(1+4)-ß-D- fucopyranoside. A synthesis of a sucrose derivative suitable for selective acylation at OH-2, OH-3 and/or OH-4 is also described. Furthermore, reductive opening of acrolein acetals with sodium cyanoborohydride/hydrogen chloride and of benzylidene acetals with borane trimethylamine/aluminium chloride is examined. The dependency of regioselectivity on solvent and reagents is investigated.  

sted, utgiver, år, opplag, sider
Stockholm: Stockholm University, 1985. , s. 38
Serie
Chemical communications, ISSN 0366-5607 ; 1985:5
HSV kategori
Identifikatorer
URN: urn:nbn:se:su:diva-174577Libris ID: 7608702ISBN: 91-7146-670-3 (tryckt)OAI: oai:DiVA.org:su-174577DiVA, id: diva2:1358717
Disputas
1985-12-06, Hörsal G, Biologilaboratoriet, Svante Arrhenius väg 16, Stockholm, 10:00
Merknad

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Tilgjengelig fra: 2019-10-08 Laget: 2019-10-08 Sist oppdatert: 2019-12-04bibliografisk kontrollert

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