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Fast and Robust Synthesis of Metalated PCN-222 and Their Catalytic Performance in Cycloaddition Reactions with CO2
Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för organisk kemi.ORCID-id: 0000-0003-0024-1392
Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för organisk kemi.ORCID-id: 0000-0002-1729-598X
Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för organisk kemi.ORCID-id: 0000-0002-7898-317X
Rekke forfattare: 32019 (engelsk)Inngår i: Organometallics, ISSN 0276-7333, E-ISSN 1520-6041, Vol. 38, nr 18, s. 3429-3435Artikkel i tidsskrift (Fagfellevurdert) Published
Abstract [en]

A simple and quick setup for the synthesis of PCN-222 and of a variety of metalated PCN-222(Co, Ni, Cu, and Zn), using of a microwave reactor, is reported for CO2 fixation. Metalation of prophyrins by microwave heating has been evaluated through UV-vis titration. PCN-222(M) were obtained in a three-step, one-pot reaction in a remarkable 72% yield in only 30 min. The materials have been characterized using a variety of techniques. A study of CO2 fixation through cycloaddition with epoxides and azidirines using metalated PCNs as catalysts is described. Cyclic carbonates and oxazolidinones were formed using CO2 at atmospheric pressure under mild conditions. Higher activity was observed when PCN-222(Co) was used compared to that with PCN-222(Ni, Cu, Zn).

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2019. Vol. 38, nr 18, s. 3429-3435
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URN: urn:nbn:se:su:diva-175708DOI: 10.1021/acs.organomet.9b00273ISI: 000487769900007OAI: oai:DiVA.org:su-175708DiVA, id: diva2:1369944
Tilgjengelig fra: 2019-11-13 Laget: 2019-11-13 Sist oppdatert: 2019-12-12bibliografisk kontrollert

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