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Amorphous-like thermal conductivity and high mechanical stability of cyclopentane clathrate hydrate
Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).ORCID-id: 0000-0003-2001-4410
Rekke forfattare: 42024 (engelsk)Inngår i: Physical Chemistry, Chemical Physics - PCCP, ISSN 1463-9076, E-ISSN 1463-9084, Vol. 26, nr 22, s. 16017-16025Artikkel i tidsskrift (Fagfellevurdert) Published
Abstract [en]

The thermal conductivity κ of cyclopentane clathrate hydrate (CP CH) of type II was measured at temperatures down to 100 K and at pressures up to 1.3 GPa. The results show that CP CH displays amorphous-like κ characteristic of many crystalline clathrate hydrates, e.g., tetrahydrofuran (THF) CH. The magnitude of κ is 0.47 W m−1 K−1 near the melting point of 280 K at atmospheric pressure, and it is almost independent of pressure and temperature T: ln κ = −0.621−40.1/T at atmospheric pressure (in SI-units). This is slightly less than κ of type II CHs of water-miscible solvents such as THF. Intriguingly, unlike other water-rich type II clathrate hydrates of water-miscible molecules M (M·17 H2O), CP CH does not amorphize at pressures up to 1.3 GPa at 130 K and also remains stable up to 0.5 GPa at 240 K. This shows that CP CH is mechanically more stable than the previously studied water-rich type II CHs, and suggests that repulsive forces between CP and the H2O cages increase the mechanical stability of crystalline CP CH. Moreover, we show that κ of an ice-CH mixture, which often arises for CHs that form naturally, is described by the average of the parallel and series heat conduction models to within 5% for ice contents up to 22 wt%. The findings provide a better understanding of the thermal and stability properties of clathrate hydrates for their applications such as gas storage compounds.

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2024. Vol. 26, nr 22, s. 16017-16025
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URN: urn:nbn:se:su:diva-232255DOI: 10.1039/d4cp01656dISI: 001228729600001PubMedID: 38775259Scopus ID: 2-s2.0-85193815393OAI: oai:DiVA.org:su-232255DiVA, id: diva2:1887838
Tilgjengelig fra: 2024-08-09 Laget: 2024-08-09 Sist oppdatert: 2024-08-09bibliografisk kontrollert

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