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Synthesis of the Lewis b pentasaccharide and a HSA-conjugate thereof
Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för organisk kemi.
Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för organisk kemi.
Vise andre og tillknytning
2010 (engelsk)Inngår i: Tetrahedron, ISSN 0040-4020, E-ISSN 1464-5416, Vol. 66, nr 39, s. 7850-7855Artikkel i tidsskrift (Fagfellevurdert) Published
Abstract [en]

Helicobacter pylori, a gastric pathogen, binds to various blood group antigens, including the Lewis types, present in the gastric tissue and a relation between the presentation of the ligands and the overall strength of binding has been assumed. Synthetic Lewis b tetra- and hexasaccharide conjugates are available but not the analogous pentasaccharide. An efficient synthesis of the amino spacer equipped Lewis b pentasaccharide, 3-aminopropyl alpha-L-fucopyranosyl-(1 -> 2)-beta-D-galactopyranosyl-(1 3)-[alpha-L-fucopyranosyl-(1 -> 4)]-2-acetamido-2-deoxy-beta-D-glucopyranosyl-(1 -> 3)-beta-D-galactopyranoside, is presented to enable further investigation of the carbohydrate recognition process of H. pylori.

sted, utgiver, år, opplag, sider
2010. Vol. 66, nr 39, s. 7850-7855
Emneord [en]
Glycosylation, Regioselective 3, 4-benzylidene opening, Glycoconjugates, Helicobacter pylori, Carbohydrate synthesis
HSV kategori
Forskningsprogram
organisk kemi
Identifikatorer
URN: urn:nbn:se:su:diva-50074DOI: 10.1016/j.tet.2010.07.036ISI: 000282071100020OAI: oai:DiVA.org:su-50074DiVA, id: diva2:382688
Merknad
authorCount :5Tilgjengelig fra: 2011-01-03 Laget: 2010-12-21 Sist oppdatert: 2017-12-11bibliografisk kontrollert

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