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Formation and decay of core-orbital vacancies in the water molecule
Stockholms universitet, Naturvetenskapliga fakulteten, Fysikum.
Vise andre og tillknytning
2013 (engelsk)Inngår i: Chemical Physics Letters, ISSN 0009-2614, E-ISSN 1873-4448, Vol. 558, s. 82-87Artikkel i tidsskrift (Fagfellevurdert) Published
Abstract [en]

Primary steps in the interaction of high energy photons with water creating multiply ionised products are examined experimentally and theoretically. Double Auger decay from a 1s-hole state populates triply ionised states between 80 and 140 eV binding energy. Ejection of one 1s electron and one valence electron gives states around 570 eV which decay to triply ionised states between 75 and 110 eV. Nuclear motion in these states competes with Auger decay and substantially modifies the final state spectra. The double core-hole state from ionisation of both 1s electrons is found at 1171 +/- 1 eV and calculated at 1170.85 eV.

sted, utgiver, år, opplag, sider
2013. Vol. 558, s. 82-87
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Identifikatorer
URN: urn:nbn:se:su:diva-88275DOI: 10.1016/j.cplett.2012.11.094ISI: 000314660600016Scopus ID: 2-s2.0-84873183578OAI: oai:DiVA.org:su-88275DiVA, id: diva2:610803
Forskningsfinansiär
Swedish Research CouncilKnut and Alice Wallenberg FoundationEU, European Research Council, R II 3-CT-2004-506008
Merknad

AuthorCount:7;

Tilgjengelig fra: 2013-03-13 Laget: 2013-03-12 Sist oppdatert: 2022-10-06bibliografisk kontrollert

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