Ändra sökning
RefereraExporteraLänk till posten
Permanent länk

Direktlänk
Referera
Referensformat
  • apa
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Annat format
Fler format
Språk
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Annat språk
Fler språk
Utmatningsformat
  • html
  • text
  • asciidoc
  • rtf
Effect of partial linker fluorination and linker extension on structure and properties of the Al-MOF CAU-10
Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).ORCID-id: 0000-0001-9118-1342
Antal upphovsmän: 42017 (Engelska)Ingår i: Microporous and Mesoporous Materials, ISSN 1387-1811, E-ISSN 1873-3093, Vol. 249, s. 128-136Artikel i tidskrift (Refereegranskat) Published
Abstract [en]

The systematic investigation of the solvothermal system Al3+/5-fluoroisophthalic acid (H(2)mBDC-5F)/isophthalic acid (H(2)mBDC)/DMF/H2O through a mixed-linker approach led to new mixed-linker CAU-10 derivatives containing 11, 28 and 44% of fluorinated linker molecules (denoted as CAU-10-H/F-11, CAU-10-H/F-28 and CAU-10-H/F-44, respectively), as determined by NMR spectroscopy. The crystal structure of CAU-10-H/F-28 was determined using the Rietveld method (space group 14(1)md, a = b = 21.3075(5), c = 10.7101(3) angstrom). The structure is built up by helical chains composed of cis corner-sharing AlO6 polyhedra. Each of these helices is interconnected to four adjacent helices with alternating rotational orientation through the carboxylate groups of mBDC(2-) linker molecules. Thus, accessible, square-shaped channels are formed. Sorption measurements revealed a high dependency of the adsorbed amount of gas on the degree of fluorination. With increasing fluorination, the total uptake decreases in N-2, H-2 and H2O sorption experiments and the hydrophobic character of the pores increases. In addition, an extended CAU-10 derivative, CAU-10-HTATB, was discovered using the tricarboxylic acid 4,4',4-s-triazine-2,4,6-triyl-tribenzoic acid (H(3)TATB) during the high-throughput investigation of the system Al3+/H(3)TATB/DMF/H2O. This new MOF, which was denoted CAU-10-HTATB, was thoroughly characterized using IR spectroscopy, thermogravimetric and elemental analysis, temperature dependent powder X-ray diffraction (PXRD) and sorption measurements. Although the compound is thermally stable up to 400 degrees C according to temperature-dependent PXRD measurements, it is not porous towards N2 molecules. The structure of CAU-10-HTATB could be also refined from PXRD data using the Rietveld method (space group l4(1)/a, a = b = 36.438 (1), c = 10.9373 (9) angstrom).

Ort, förlag, år, upplaga, sidor
2017. Vol. 249, s. 128-136
Nyckelord [en]
Metal-organic frameworks, Aluminium, Powder X-ray diffraction, CAU-10, Water sorption
Nationell ämneskategori
Kemi Nanoteknik Materialteknik
Identifikatorer
URN: urn:nbn:se:su:diva-145962DOI: 10.1016/j.micromeso.2017.04.054ISI: 000404315500016OAI: oai:DiVA.org:su-145962DiVA, id: diva2:1141798
Tillgänglig från: 2017-09-15 Skapad: 2017-09-15 Senast uppdaterad: 2020-05-09Bibliografiskt granskad

Open Access i DiVA

Fulltext saknas i DiVA

Övriga länkar

Förlagets fulltext

Sök vidare i DiVA

Av författaren/redaktören
Inge, A. Ken
Av organisationen
Institutionen för material- och miljökemi (MMK)
I samma tidskrift
Microporous and Mesoporous Materials
KemiNanoteknikMaterialteknik

Sök vidare utanför DiVA

GoogleGoogle Scholar

doi
urn-nbn

Altmetricpoäng

doi
urn-nbn
Totalt: 120 träffar
RefereraExporteraLänk till posten
Permanent länk

Direktlänk
Referera
Referensformat
  • apa
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Annat format
Fler format
Språk
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Annat språk
Fler språk
Utmatningsformat
  • html
  • text
  • asciidoc
  • rtf