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SU-75: a disordered Ge-10 germanate with pcu topology
Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
Visa övriga samt affilieringar
2012 (Engelska)Ingår i: Dalton Transactions, ISSN 1477-9226, E-ISSN 1477-9234, Vol. 41, nr 40, s. 12358-12364Artikel i tidskrift (Refereegranskat) Published
Abstract [en]

A disordered open-framework germanate, denoted as SU-75, was synthesized under hydrothermal conditions using diethylenetriamine (dien) or alternatively 1,4-diaminobutane (dab) as the structure directing agent (SDA). SU-75 crystallizes in a tetragonal space group I-42d(No. 122) with a= 18.145(3) Å and c= 41.701(9) Å. The three-dimensional (3D) framework is built from Ge10(O,OH)28(Ge10) clusters that are connected following the pcu ( primitive cubic) net topology. SU-75 has 10-, 11- and 12-ring channels along the a- and b-axes and channels with alternating 8-, 10-, 12-, 10-ring openings along the c-axis. The framework exhibits a serious disorder, resulted from two possible connectivities between the units of four Ge 10clusters (4Ge10 unit). The chemical formula of SU-75 is |(H2SDA)2(H2O)n|[Ge10O21(OH)2] (SDA = dien or dab,n= 5–6), determined by combining single crystalsynchrotron X-ray diffraction, thermogravimetric analysis (TGA) and CHN elemental analysis. A superoctahedron is introduced to simplify the description of the connectivity of the Ge10 clusters and to illustrate the disorder. This is also used to compare the structure of SU-75 with those of related Ge10 germanates.

Ort, förlag, år, upplaga, sidor
2012. Vol. 41, nr 40, s. 12358-12364
Nyckelord [en]
Germanate, Ge10, pcu topology
Nationell ämneskategori
Oorganisk kemi
Forskningsämne
strukturkemi
Identifikatorer
URN: urn:nbn:se:su:diva-80852DOI: 10.1039/c2dt30767gISI: 000309141500005OAI: oai:DiVA.org:su-80852DiVA, id: diva2:557857
Tillgänglig från: 2012-10-25 Skapad: 2012-09-30 Senast uppdaterad: 2017-12-07Bibliografiskt granskad
Ingår i avhandling
1. Open-Framework Germanates and Nickel Germanates: Synthesis and Characterization
Öppna denna publikation i ny flik eller fönster >>Open-Framework Germanates and Nickel Germanates: Synthesis and Characterization
2012 (Engelska)Doktorsavhandling, sammanläggning (Övrigt vetenskapligt)
Abstract [en]

Microporous materials have a wide range of important applications in separation, gas adsorption, ion-exchange and catalysis. Open-framework germanates are a family of microporous compounds and are of particular interest. This thesis focuses on the synthesis and characterization of new open-framework germanates as well as introducing the transition-metal nickel into germanate structures.

One new microporous germanosilicate, SU-78 and four new open-framework germanates, SU-74, SU-75, SU-69 and SU-76 have been obtained by using organic molecules as structure directing agents (SDAs). The incorporation of nickel and organic SDAs in the synthesis resulted in five novel nickel germanates, SUT-1, SUT-2, SUT-3, SUT-4 and SUT-5, in which nickel complexes act either as framework-forming components or as structure directing agents.

The general synthesis route is described and the variables that affect the synthesis products are summarized. Different techniques applied on the characterization of chemical and physical properties of the products are also introduced.

Ort, förlag, år, upplaga, sidor
Stockholm: Department of Materials and Environmental Chemistry (MMK), Stockholm University, 2012. s. 81
Nyckelord
open-framework, zeolites, germanates, nickel germanates, structure directing agent, nickel complexes, crystal structure determination, hydrothermal synthesis
Nationell ämneskategori
Oorganisk kemi
Forskningsämne
strukturkemi
Identifikatorer
urn:nbn:se:su:diva-75495 (URN)978-91-7447-489-3 (ISBN)
Disputation
2012-05-30, Magnélisalen, Kemiska övningslaboratoriet, Svante Arrhenius väg 16 B, Stockholm, 10:00 (Engelska)
Opponent
Handledare
Anmärkning

At the time of the doctoral defense, the following papers were unpublished and had a status as follows: Paper 1: Submitted. Paper 2: Submitted. Paper 3: Submitted. Paper 5: Manuscript.

Tillgänglig från: 2012-05-08 Skapad: 2012-04-20 Senast uppdaterad: 2012-10-25Bibliografiskt granskad
2. Open-Framework Germanates: Synthesis, Structure, and Characterization
Öppna denna publikation i ny flik eller fönster >>Open-Framework Germanates: Synthesis, Structure, and Characterization
2012 (Engelska)Doktorsavhandling, sammanläggning (Övrigt vetenskapligt)
Abstract [en]

Novel open-framework germanates and open low-dimensional structures were synthesized and characterized. Their crystal structures were solved by single crystal X-ray diffraction or X-ray powder diffraction combined with other techniques. Although related open-framework materials, such as zeolites, are of interest for the ability to selectively accommodate guest species in their rings, pores and channels, germanates are primarily of interest for their unique structural properties. Compared to aluminosilicate-based zeolites, germanium oxides readily form frameworks with extra-large rings and low framework density. The formation of elegant germanate architectures is attributed to the unique Ge-O bond geometries compared to Si-O, and the tendency to form large clusters.

This thesis is to serve as an introduction to germanate synthesis, structures and characterization. Structures are categorized in accordance to their building units; the Ge7X19 (Ge7), Ge9X25-26 (Ge9) and Ge10X28 (Ge10) (X = O, OH, or F) clusters. Structure determination techniques as well as the characterization techniques used to examine the properties of the materials are presented. While most of the discussed techniques have routinely been used to study crystalline open-frameworks, we introduce the use of infrared spectroscopy for the identification of cluster types, valuable for structure determination by X-ray powder diffraction. Structures and properties of the novel materials ASU-21, SU-62, SU-63, SU-64, SU-65, SU-66, SU-71, SU-72, SU-73, SU-74, SU-75 and SU-JU-14 are described and put into context with previously known structures. The novel structures are all built of the Ge7, Ge9 or Ge10 clusters, and vary from a framework with novel topology to the first open zero-dimensional germanate cavities built of such clusters.

Ort, förlag, år, upplaga, sidor
Stockholm: Department of Materials and Environmental Chemistry (MMK), Stockholm University, 2012. s. 120
Nyckelord
Open-framework, zeolites, germanates, porous materials, crystallography, hydrothermal synthesis, crystal structure
Nationell ämneskategori
Oorganisk kemi
Forskningsämne
strukturkemi
Identifikatorer
urn:nbn:se:su:diva-75732 (URN)978-91-7447-519-7 (ISBN)
Disputation
2012-06-13, Magnélisalen, Kemiska övningslaboratoriet, Svante Arrhenius väg 16 B, Stockholm, 13:00 (Engelska)
Opponent
Handledare
Anmärkning

At the time of the doctoral defense, the following papers were unpublished and had a status as follows: Paper 2: Submitted. Paper 3: Manuscript. Paper 4: Submitted. Paper 6: Submitted. Paper 7: Manuscript. Paper 8. Manuscript. Paper 10: Unpublished book chapter.

 

Tillgänglig från: 2012-05-10 Skapad: 2012-04-26 Senast uppdaterad: 2012-10-25Bibliografiskt granskad

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