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A series of inorganic-organic hybrid cadmium borates with novel Cd-centred [Cd@B14O20(OH)(6)](2-) clusters
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Rekke forfattare: 52016 (engelsk)Inngår i: Dalton Transactions, ISSN 1477-9226, E-ISSN 1477-9234, Vol. 45, nr 35, s. 13937-13943Artikkel i tidsskrift (Fagfellevurdert) Published
Abstract [en]

Four novel inorganic-organic hybrid cadmium borates, namely [EAH](2){(py)(2)Cd@[B14O20-(OH)(6)]} (1, py = pyridine, EA = ethylamine), [PAH](2){(py)(2)Cd@[B14O20(OH)(6)]} (2, PA = propylamine), [pyH](2){(py)(2)Cd@ [B14O20(OH)(6)]} (3) and {(AImH)(2)Cd@[B14O20(OH)(6)]} (4, AIm = 1-(3-aminopropyl) imidazole) have been solvothermally synthesized and characterized by elemental analysis, thermogravimetric analysis, IR spectroscopy, UV-Vis-NIR spectroscopy, fluorescence spectroscopy, powder X-ray diffraction, and single-crystal X-ray diffraction, respectively. They represent the first hybrid cadmium borates that exhibit 3D supramolecular open-frameworks with different topologies. All the networks are formed by the unprecedented Cd-centred cluster [Cd@B14O20(OH)(6)](2-), and further link each other via a multipoint H-bond system. UV-Vis-NIR spectral investigation reveals that these borates are wide-band-gap semiconductors. Moreover, they display strong fluorescence emission around 430 nm, making them excellent candidates for optoelectronic applications as blue materials.

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2016. Vol. 45, nr 35, s. 13937-13943
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URN: urn:nbn:se:su:diva-134191DOI: 10.1039/c6dt02875fISI: 000382745900035PubMedID: 27523170OAI: oai:DiVA.org:su-134191DiVA, id: diva2:1040493
Tilgjengelig fra: 2016-10-27 Laget: 2016-10-03 Sist oppdatert: 2017-11-29bibliografisk kontrollert

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