Endre søk
RefereraExporteraLink to record
Permanent link

Direct link
Referera
Referensformat
  • apa
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Annet format
Fler format
Språk
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Annet språk
Fler språk
Utmatningsformat
  • html
  • text
  • asciidoc
  • rtf
Anti-Stokes resonant x-ray Raman scattering for atom specific and excited state selective dynamics
Stockholms universitet, Naturvetenskapliga fakulteten, Fysikum.ORCID-id: 0000-0002-8621-4282
Stockholm Univ, Dept Phys, AlbaNova Univ Ctr, SE-10691 Stockholm, Sweden.
Vise andre og tillknytning
Rekke forfattare: 202016 (engelsk)Inngår i: New Journal of Physics, ISSN 1367-2630, E-ISSN 1367-2630, Vol. 18, artikkel-id 103011Artikkel i tidsskrift (Fagfellevurdert) Published
Abstract [en]

Ultrafast electronic and structural dynamics of matter govern rate and selectivity of chemical reactions, as well as phase transitions and efficient switching in functional materials. Since x-rays determine electronic and structural properties with elemental, chemical, orbital and magnetic selectivity, short pulse x-ray sources have become central enablers of ultrafast science. Despite of these strengths, ultrafast x-rays have been poor at picking up excited state moieties from the unexcited ones. With time-resolved anti-Stokes resonant x-ray Raman scattering (AS-RXRS) performed at the LCLS, and ab initio theory we establish background free excited state selectivity in addition to the elemental, chemical, orbital and magnetic selectivity of x-rays. This unparalleled selectivity extracts low concentration excited state species along the pathway of photo induced ligand exchange of Fe(CO)(5) in ethanol. Conceptually a full theoretical treatment of all accessible insights to excited state dynamics with AS-RXRS with transform-limited x-ray pulses is given-which will be covered experimentally by upcoming transform-limited x-ray sources.

sted, utgiver, år, opplag, sider
2016. Vol. 18, artikkel-id 103011
Emneord [en]
ultrafast photochemistry, excited state selectivity, anti-Stokes resonant x-ray raman scattering, free electron lasers, resonant inelastic x-ray scattering
HSV kategori
Identifikatorer
URN: urn:nbn:se:su:diva-136093DOI: 10.1088/1367-2630/18/10/103011ISI: 000386047000005OAI: oai:DiVA.org:su-136093DiVA, id: diva2:1052773
Tilgjengelig fra: 2016-12-07 Laget: 2016-11-29 Sist oppdatert: 2019-12-17bibliografisk kontrollert

Open Access i DiVA

Fulltekst mangler i DiVA

Andre lenker

Forlagets fulltekst

Søk i DiVA

Av forfatter/redaktør
Josefsson, IdaSchreck, SimonOdelius, Michael
Av organisasjonen
I samme tidsskrift
New Journal of Physics

Søk utenfor DiVA

GoogleGoogle Scholar

doi
urn-nbn

Altmetric

doi
urn-nbn
Totalt: 9 treff
RefereraExporteraLink to record
Permanent link

Direct link
Referera
Referensformat
  • apa
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Annet format
Fler format
Språk
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Annet språk
Fler språk
Utmatningsformat
  • html
  • text
  • asciidoc
  • rtf