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Evolution and Prospects of the Asymmetric Hydrogenation of Unfunctionalized Olefins
Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för organisk kemi.
Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för organisk kemi.ORCID-id: 0000-0002-1383-8246
Rekke forfattare: 22017 (engelsk)Inngår i: Journal of the American Chemical Society, ISSN 0002-7863, E-ISSN 1520-5126, Vol. 139, nr 4, s. 1346-1356Artikkel i tidsskrift (Fagfellevurdert) Published
Abstract [en]

The catalytic enantioselective hydrogenation of prochiral olefins is a key reaction in asymmetric synthesis. Its relevance applies to both industry and academia as an inherently direct and sustainable strategy to induce chirality. Here we briefly recount the early breakthroughs concerning the asymmetric hydrogenation of largely unfunctionalized olefins, from the first reports to the advent of chiral Crabtree-like catalysts. The mechanism and its implications on the enantioselectivity are shortly discussed. The main focus of this Perspective lies on the more recent advances in the field, such as the latest developed classes of ligands and the opportunity to employ more Earth-abundant metals. Therefore, separate sections consider iridium N,P-, NHC-, P,S-, and O,P catalysts, and rhodium, palladium, cobalt, and iron catalysts. Finally, the remaining unsolved challenges are examined, and the potential directions of forthcoming research are outlined.

sted, utgiver, år, opplag, sider
2017. Vol. 139, nr 4, s. 1346-1356
HSV kategori
Forskningsprogram
organisk kemi
Identifikatorer
URN: urn:nbn:se:su:diva-141378DOI: 10.1021/jacs.6b10690ISI: 000393355600001PubMedID: 28064490OAI: oai:DiVA.org:su-141378DiVA, id: diva2:1091936
Forskningsfinansiär
Knut and Alice Wallenberg FoundationStiftelsen Olle Engkvist ByggmästareTilgjengelig fra: 2017-04-28 Laget: 2017-04-28 Sist oppdatert: 2019-12-04bibliografisk kontrollert

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