Change search
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf
Selective Palladium-Catalyzed Allenic C-H Bond Oxidation for the Synthesis of [3]Dendralenes
Stockholm University, Faculty of Science, Department of Organic Chemistry.
Stockholm University, Faculty of Science, Department of Organic Chemistry.
Stockholm University, Faculty of Science, Department of Organic Chemistry.ORCID iD: 0000-0001-8462-4176
2017 (English)In: Angewandte Chemie International Edition, ISSN 1433-7851, E-ISSN 1521-3773, Vol. 56, no 42, p. 13112-13116Article in journal (Refereed) Published
Abstract [en]

A highly selective palladium-catalyzed allenic C-H bond oxidation was developed, and it provides a novel and straightforward synthesis of [3]dendralene derivatives. A variety of [3]dendralenes with diverse substitution patterns are accessible with good efficiency and high stereoselectivity. The reaction tolerates a broad substrate scope containing various functional groups on the allene moiety, including ketone, aldehyde, ester, and phenyl groups. Also, a wide range of olefins with both electron-donating and electron-withdrawing aryls, acrylate, sulfone, and phosphonate groups are tolerated.

Place, publisher, year, edition, pages
Wiley-VCH Verlagsgesellschaft, 2017. Vol. 56, no 42, p. 13112-13116
Keywords [en]
dendralenes, allenes, olefination, palladium, regioselectivity
National Category
Organic Chemistry
Identifiers
URN: urn:nbn:se:su:diva-147910DOI: 10.1002/anie.201706211ISI: 000412189700058PubMedID: 28799682OAI: oai:DiVA.org:su-147910DiVA, id: diva2:1149863
Funder
EU, European Research CouncilSwedish Research CouncilBerzelii Centre EXSELENTKnut and Alice Wallenberg FoundationAvailable from: 2017-10-17 Created: 2017-10-17 Last updated: 2019-02-15Bibliographically approved

Open Access in DiVA

fulltext(1109 kB)38 downloads
File information
File name FULLTEXT01.pdfFile size 1109 kBChecksum SHA-512
1a9e256bcf5bf9f8f66482c6a2a6fa186d2335baccb2726cf1d845bf5e0520b5cccfa130efd297f7994500fd0ae3e6a2423f6dd719cf79950a442fbd61f6b3f7
Type fulltextMimetype application/pdf

Other links

Publisher's full textPubMed

Search in DiVA

By author/editor
Qiu, YouaiPosevins, DanielsBäckvall, Jan-E.
By organisation
Department of Organic Chemistry
In the same journal
Angewandte Chemie International Edition
Organic Chemistry

Search outside of DiVA

GoogleGoogle Scholar
Total: 38 downloads
The number of downloads is the sum of all downloads of full texts. It may include eg previous versions that are now no longer available

doi
pubmed
urn-nbn

Altmetric score

doi
pubmed
urn-nbn
Total: 48 hits
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf