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Lignin depolymerization to monophenolic compounds in a flow-through system
Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för organisk kemi.
Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för organisk kemi.
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Rekke forfattare: 62017 (engelsk)Inngår i: Green Chemistry, ISSN 1463-9262, E-ISSN 1463-9270, Vol. 19, nr 24, s. 5767-5771Artikkel i tidsskrift (Fagfellevurdert) Published
Abstract [en]

A reductive lignocellulose fractionation in a flow-through system in which pulping and transfer hydrogenolysis steps were separated in time and space has been developed. Without the hydrogenolysis step or addition of trapping agents to the pulping, it is possible to obtain partially depolymerized lignin (21 wt% monophenolic compounds) that is prone to further processing. By applying a transfer hydrogenolysis step 37 wt% yield of lignin derived monophenolic compounds was obtained. Pulp generated in the process was enzymatically hydrolyzed to glucose in 87 wt% yield without prior purification.

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2017. Vol. 19, nr 24, s. 5767-5771
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URN: urn:nbn:se:su:diva-151203DOI: 10.1039/c7gc02731aISI: 000417756500003OAI: oai:DiVA.org:su-151203DiVA, id: diva2:1172968
Tilgjengelig fra: 2018-01-11 Laget: 2018-01-11 Sist oppdatert: 2018-01-11bibliografisk kontrollert

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Kumaniaev, IvanSubbotina, ElenaGalkin, Maxim V.Samec, Joseph S. M.
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