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Design and synthesis of biobased epoxy thermosets from biorenewable resources
Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för organisk kemi.
Vise andre og tillknytning
Rekke forfattare: 122017 (engelsk)Inngår i: Comptes rendus. Chimie, ISSN 1631-0748, E-ISSN 1878-1543, Vol. 20, nr 11-12, s. 1006-1016Artikkel i tidsskrift (Fagfellevurdert) Published
Abstract [en]

Biobased diepoxy synthons derived from isoeugenol, eugenol or resorcinol (DGE-isoEu, DGE-Eu and DGER, respectively) have been used as epoxy monomers in replacement of the diglycidyl ether of bisphenol A (DGEBA). Their curing with six different biobased anhydride hardeners leads to fully biobased epoxy thermosets. These materials exhibit interesting thermal and mechanical properties comparable to those obtained with conventional petrosourced DGEBA-based epoxy resins cured in similar conditions. In particular, a high T-g in the range of 90-130 degrees C and instantaneous moduli higher than 4.3 GPa have been recorded. These good performances are very encouraging, making these new fully biobased epoxy thermosets compatible with the usual structural application of epoxy materials.

sted, utgiver, år, opplag, sider
2017. Vol. 20, nr 11-12, s. 1006-1016
Emneord [en]
Biobased resins, DEGBA alternative, Epoxy-anhydride thermosets, Curing process, Nanoindentation
HSV kategori
Identifikatorer
URN: urn:nbn:se:su:diva-152656DOI: 10.1016/j.crci.2017.10.005ISI: 000418629300004OAI: oai:DiVA.org:su-152656DiVA, id: diva2:1182191
Tilgjengelig fra: 2018-02-12 Laget: 2018-02-12 Sist oppdatert: 2018-02-12bibliografisk kontrollert

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Rautiainen, SariSamec, Joseph
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