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One-dimensional cuts through multidimensional potential-energy surfaces by tunable x rays
Stockholms universitet, Naturvetenskapliga fakulteten, Fysikum.ORCID-id: 0000-0002-4603-2097
Vise andre og tillknytning
Rekke forfattare: 142018 (engelsk)Inngår i: Physical Review A: covering atomic, molecular, and optical physics and quantum information, ISSN 2469-9926, E-ISSN 2469-9934, Vol. 97, nr 5, artikkel-id 053410Artikkel i tidsskrift (Fagfellevurdert) Published
Abstract [en]

The concept of the potential-energy surface (PES) and directional reaction coordinates is the backbone of our description of chemical reaction mechanisms. Although the eigenenergies of the nuclear Hamiltonian uniquely link a PES to its spectrum, this information is in general experimentally inaccessible in large polyatomic systems. This is due to (near) degenerate rovibrational levels across the parameter space of all degrees of freedom, which effectively forms a pseudospectrum given by the centers of gravity of groups of close-lying vibrational levels. We show here that resonant inelastic x-ray scattering (RIXS) constitutes an ideal probe for revealing one-dimensional cuts through the ground-state PES of molecular systems, even far away from the equilibrium geometry, where the independent-mode picture is broken. We strictly link the center of gravity of close-lying vibrational peaks in RIXS to a pseudospectrum which is shown to coincide with the eigenvalues of an effective one-dimensional Hamiltonian along the propagation coordinate of the core-excited wave packet. This concept, combined with directional and site selectivity of the core-excited states, allows us to experimentally extract cuts through the ground-state PES along three complementary directions for the showcase H2O molecule.

sted, utgiver, år, opplag, sider
2018. Vol. 97, nr 5, artikkel-id 053410
Emneord [en]
Molecular spectra, Potential energy surfaces, Single- and few-photon ionization & excitation, Ultrafast phenomena
HSV kategori
Identifikatorer
URN: urn:nbn:se:su:diva-157740DOI: 10.1103/PhysRevA.97.053410ISI: 000433002600009OAI: oai:DiVA.org:su-157740DiVA, id: diva2:1236307
Tilgjengelig fra: 2018-08-01 Laget: 2018-08-01 Sist oppdatert: 2019-12-17bibliografisk kontrollert

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Ertan, EmelieOdelius, Michael
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