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Cyclic allylic carbonates as a renewable platform for protecting chemistry in water
Stockholm University, Faculty of Science, Department of Organic Chemistry.
Stockholm University, Faculty of Science, Department of Organic Chemistry.
Stockholm University, Faculty of Science, Department of Organic Chemistry.
Stockholm University, Faculty of Science, Department of Organic Chemistry.
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Number of Authors: 62018 (English)In: Green Chemistry, ISSN 1463-9262, E-ISSN 1463-9270, Vol. 20, no 14, p. 3186-3190Article in journal (Refereed) Published
Abstract [en]

The present work explores different cyclic allylic carbonates as a potential class of allylcarbamate precursors. The 5-membered carbonate formed a carbamate with very good thermal and pH stability, which could be cleanly deprotected in aqueous solution, in just 30 min with 2 mol% Pd(OAc)(2) as catalyst. The polar nature of the installed motif made it possible to deprotect highly unpolar substrates in water as solvent.

Place, publisher, year, edition, pages
2018. Vol. 20, no 14, p. 3186-3190
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Organic Chemistry
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URN: urn:nbn:se:su:diva-159054DOI: 10.1039/c8gc01622dISI: 000438937500003OAI: oai:DiVA.org:su-159054DiVA, id: diva2:1243954
Available from: 2018-08-31 Created: 2018-08-31 Last updated: 2018-08-31Bibliographically approved

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Morvan, JenniferSawadjoon, SupapornShatskiy, AndreyÅkermark, Björn
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