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Self-cleaned photoluminescent viscose fabric incorporated lanthanide-organic framework (Ln-MOF)
Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK). Assuit University, Egypt.
Rekke forfattare: 32018 (engelsk)Inngår i: Dyes and pigments, ISSN 0143-7208, E-ISSN 1873-3743, Vol. 159, s. 491-498Artikkel i tidsskrift (Fagfellevurdert) Published
Abstract [en]

Photoluminescent textiles emitted light in ultraviolet (UV)-radiation region has advanced a variety of applications including military and police clothes. The current study reports the preparation of photoluminescent viscose fabrics incorporated lanthanide metal-organic framework (Ln-MOF) and their applications for self-cleaning. In situ growth of Ln (Eu3+, Tb3+) MOF into viscose fabrics were achieved using Ln (NO3)(3) and 1,2,4,5-benzenetetracarboxylic dianhydride as organic ligand. The in-growth Ln-MOF within fabrics were characterized using X-ray diffraction, Fourier transform infrared spectroscopy, scanning electron microscope, energy dispersive X-ray, and fluorescence spectroscopy. Under the UV lamb (345 nm), Eu-MOF@viscose fabric and Tb-MOF@viscose fabric visually emitted red and green color, respectively. The excitation-emission spectra showed the spectra for the D-5(0)-> F-7(0.4) transitions and D-5(4)-> F-7(5) transitions in case of Eu-MOF and Tb-MOF@viscose fabrics, respectively. The photoluminescent properties of Ln-MOF@viscose fabrics were enhanced after reactive dying process. The self-cleaning functions of Ln-MOF@viscose fabrics were estimated through studying the photo-degradation of Rhodamine B (RhB) dye over the fabrics. After 120 min irradiation time, the photo-degradation of RhB dye was 85-97%, indicating high performance of Ln-MOF@viscose fabric. The materials are promising for advanced applications including protective clothing, textile-based sensors, smart tagging and tickets.

sted, utgiver, år, opplag, sider
2018. Vol. 159, s. 491-498
Emneord [en]
Viscose fabric, Ln-MOF, Photoluminescent, Self-cleaning, Photocatalysis, Dye degradation
HSV kategori
Identifikatorer
URN: urn:nbn:se:su:diva-160176DOI: 10.1016/j.dyepig.2018.07.026ISI: 000442333700058OAI: oai:DiVA.org:su-160176DiVA, id: diva2:1251953
Tilgjengelig fra: 2018-09-28 Laget: 2018-09-28 Sist oppdatert: 2018-09-28bibliografisk kontrollert

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Emam, Hossam E.Abdelhamid, Hani Nasser
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