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Ductile Pd-Catalysed Hydrodearomatization of Phenol-Containing Bio-Oils Into Either Ketones or Alcohols using PMHS and H2O as Hydrogen Source
Stockholm University, Faculty of Science, Department of Organic Chemistry.
Stockholm University, Faculty of Science, Department of Organic Chemistry.
Stockholm University, Faculty of Science, Department of Organic Chemistry.
Stockholm University, Faculty of Science, Department of Organic Chemistry.
Number of Authors: 42018 (English)In: Advanced Synthesis and Catalysis, ISSN 1615-4150, E-ISSN 1615-4169, Vol. 360, no 20, p. 3924-3929Article in journal (Refereed) Published
Abstract [en]

A series of phenolic bio-oil components were selectively hydrodearomatized by palladium on carbon into the corresponding ketones or alcohols in excellent yields using polymethylhydrosiloxane and water as reducing agent. The selectivity of the reaction was governed by the water concentration where selectivity to alcohol was favoured at higher water concentrations. As phenolic bio-oil examples cardanol and beech wood tar creosote were studied as substrate to the developed reaction conditions. Cardanol was hydrodearomatized into 3-pentadecylcyclohexanone in excellent yield. From beech wood tar creosote, a mixture of cyclohexanols was produced. No hydrodeoxygenation occurred, suggesting the applicability of the reported method for the production of ketone-alcohol oil from biomass.

Place, publisher, year, edition, pages
2018. Vol. 360, no 20, p. 3924-3929
Keywords [en]
Beech wood tar creosote, Bio-oil, Cardanol, Heterogeneous catalysis, Hydrodearomatization, Palladium
National Category
Chemical Sciences
Identifiers
URN: urn:nbn:se:su:diva-161930DOI: 10.1002/adsc.201800614ISI: 000447633800011OAI: oai:DiVA.org:su-161930DiVA, id: diva2:1262701
Available from: 2018-11-12 Created: 2018-11-12 Last updated: 2018-11-12Bibliographically approved

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Di Francesco, DavideSubbotina, ElenaRautiainen, SariSamec, Joseph S. M.
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