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A series of isostructural mesoporous metal-organic frameworks obtained by ion-exchange induced single-crystal to single-crystal transformation
Stockholm University, Faculty of Science, Department of Materials and Environmental Chemistry (MMK).
Stockholm University, Faculty of Science, Department of Materials and Environmental Chemistry (MMK).
Stockholm University, Faculty of Science, Department of Materials and Environmental Chemistry (MMK).ORCID iD: 0000-0001-9800-3370
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Number of Authors: 62012 (English)In: Dalton Transactions, ISSN 1477-9226, E-ISSN 1477-9234, Vol. 41, no 14, p. 3953-3955Article in journal (Refereed) Published
Abstract [en]

A series of metal-organic frameworks representing a non-interpenetrated framework analogue of MOF-14 have been synthesized by using two different linkers, 4,4',4 ''-benzene-1,3,5-triyl-benzoic acid (H3BTB) and 4,4'-bipyridine (Bpy). Interestingly, the transition metal ions in the paddle-wheel metal clusters could be exchanged by other transition metal ions via a direct single-crystal to single-crystal transformation. This post-synthesis route can be used for synthesis of isomorphous metal-organic frameworks that cannot be obtained by direct synthesis.

Place, publisher, year, edition, pages
2012. Vol. 41, no 14, p. 3953-3955
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Chemical Sciences
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URN: urn:nbn:se:su:diva-162446DOI: 10.1039/c2dt12088gISI: 000301495500019PubMedID: 22301720OAI: oai:DiVA.org:su-162446DiVA, id: diva2:1267964
Available from: 2018-12-04 Created: 2018-12-04 Last updated: 2018-12-04Bibliographically approved

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Yao, QingxiaSun, JunliangSu, JieZou, Xiaodong
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