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Efficient Heterogeneous Palladium-Catalyzed Oxidative Cascade Reactions of Enallenols to Furan and Oxaborole Derivatives
Stockholm University, Faculty of Science, Department of Organic Chemistry. Anhui University, P. R. China.
Stockholm University, Faculty of Science, Department of Organic Chemistry.
Stockholm University, Faculty of Science, Department of Organic Chemistry.
Stockholm University, Faculty of Science, Department of Organic Chemistry.
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Number of Authors: 52020 (English)In: Angewandte Chemie International Edition, ISSN 1433-7851, E-ISSN 1521-3773Article in journal (Refereed) Epub ahead of print
Abstract [en]

A heterogeneous palladium-catalyzed oxidative cyclization of enallenols has been developed for the construction of highly substituted furan and oxaborole derivatives. The heterogeneous catalyst (Pd-AmP-MCF) exhibits high activity, high site- and stereoselectivity, and efficient palladium recyclability in the transformations.

Place, publisher, year, edition, pages
2020.
Keywords [en]
efficiency, heterogeneous palladium, oxidative cyclizations, stereospecific
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Chemical Sciences
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URN: urn:nbn:se:su:diva-177450DOI: 10.1002/anie.201911462ISI: 000502398300001PubMedID: 31729824OAI: oai:DiVA.org:su-177450DiVA, id: diva2:1387674
Available from: 2020-01-22 Created: 2020-01-22 Last updated: 2020-01-22

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Li, Man-BoPosevins, DanielsZhu, CanBäckvall, Jan-E.
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