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Determination of polycyclic aromatic hydrocarbons in commercial olive oils by HPLC/GC/MS – Occurrence, composition and sources
Stockholm University, Faculty of Science, Department of Environmental Science and Analytical Chemistry.ORCID iD: 0000-0003-2828-9603
Stockholm University, Faculty of Science, Department of Environmental Science and Analytical Chemistry.ORCID iD: 0000-0002-1598-7093
2022 (English)In: Food Control, ISSN 0956-7135, E-ISSN 1873-7129, Vol. 132, article id 108528Article in journal (Refereed) Published
Abstract [en]

Polycyclic aromatic hydrocarbons (PAHs) are a large class of organic compounds produced from incomplete combustion. Many PAHs are mutagenic and some are carcinogenic and pose a health risk to humans. Dietary intake of PAHs is a major route of exposure, where fats and edible oils are important contributors to overall dietary PAH exposure. Composed of hundreds of individual compounds as a complex mixture, only 16 PAHs are typically monitored in food and the environment.

In this present study we analyzed 16 commercial olive oil samples from different countries of origin and type (virgin or refined oil) for their content of 45 PAHs using a high-performance liquid chromatograph coupled to a gas chromatograph with a mass spectrometric detector. The content of the 45 PAHs varied between 9.17–94.7 μg/kg (median: 30.1 μg/kg) in the different olive oil samples. Only one sample didn't meet the regulatory threshold levels for PAHs.

The compositional profile of PAHs across the olive oil samples showed a high abundance of PAHs of lower molecular weights, and a large contribution of alkylated PAHs regardless of olive oil type. Direct contact with diesel exhaust emissions from mechanical harvesters has previously shown to affect PAH levels in olive oils. Using diagnostic PAH ratios, biomass/coal combustion and/or petroleum/fossil fuel combustion were indicated as important sources. Source apportionment by positive matrix factorization revealed diesel exhaust emission and biomass combustion as the two major sources of PAHs followed by traffic emissions. This suggests that air quality may have a considerable impact on pollution levels in olive oils and thus indirectly affect dietary exposure.

Place, publisher, year, edition, pages
2022. Vol. 132, article id 108528
Keywords [en]
polycyclic aromatic hydrocarbons, PAHs, olive oils, edible oils, positive matrix 51 factorization
National Category
Analytical Chemistry Other Chemistry Topics
Research subject
Analytical Chemistry
Identifiers
URN: urn:nbn:se:su:diva-196200DOI: 10.1016/j.foodcont.2021.108528ISI: 000709512800009OAI: oai:DiVA.org:su-196200DiVA, id: diva2:1590182
Available from: 2021-09-02 Created: 2021-09-02 Last updated: 2021-12-14Bibliographically approved

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Ekner, HollySadiktsis, Ioannis

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