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Following the Crystallization of Amorphous Ice after Ultrafast Laser Heating
Stockholm University, Faculty of Science, Department of Physics.ORCID iD: 0000-0003-1355-649x
Stockholm University, Faculty of Science, Department of Physics.ORCID iD: 0000-0002-7319-7807
Stockholm University, Faculty of Science, Department of Physics. SLAC National Accelerator Laboratory, United States.ORCID iD: 0000-0002-2174-7213
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Number of Authors: 192022 (English)In: Journal of Physical Chemistry B, ISSN 1520-6106, E-ISSN 1520-5207, Vol. 126, no 11, p. 2299-2307Article in journal (Refereed) Published
Abstract [en]

Using time-resolved wide-angle X-ray scattering, we investigated the early stages (10 μs–1 ms) of crystallization of supercooled water, obtained by the ultrafast heating of high- and low-density amorphous ice (HDA and LDA) up to a temperature T = 205 K ± 10 K. We have determined that the crystallizing phase is stacking disordered ice (Isd), with a maximum cubicity of χ = 0.6, in agreement with predictions from molecular dynamics simulations at similar temperatures. However, we note that a growing small portion of hexagonal ice (Ih) was also observed, suggesting that within our timeframe, Isd starts annealing into Ih. The onset of crystallization, in both amorphous ice, occurs at a similar temperature, but the observed final crystalline fraction in the LDA sample is considerably lower than that in the HDA sample. We attribute this discrepancy to the thickness difference between the two samples. 

Place, publisher, year, edition, pages
2022. Vol. 126, no 11, p. 2299-2307
National Category
Condensed Matter Physics
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URN: urn:nbn:se:su:diva-204017DOI: 10.1021/acs.jpcb.1c10906ISI: 000778011400016PubMedID: 35275642Scopus ID: 2-s2.0-85126546920OAI: oai:DiVA.org:su-204017DiVA, id: diva2:1652531
Available from: 2022-04-19 Created: 2022-04-19 Last updated: 2022-04-19Bibliographically approved

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Ladd-Parada, MarjorieAmann-Winkel, KatrinSpäh, AlexanderPerakis, FivosPathak, HarshadMariedahl, DanielEklund, TobiasWeston, MatthewNilsson, Anders

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