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Bi2CoO2F4─A Polar, Ferrimagnetic Aurivillius Oxide-Fluoride
Stockholm University, Faculty of Science, Department of Materials and Environmental Chemistry (MMK).
Stockholm University, Faculty of Science, Department of Materials and Environmental Chemistry (MMK).ORCID iD: 0000-0003-4319-1540
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2022 (English)In: Chemistry of Materials, ISSN 0897-4756, E-ISSN 1520-5002, Vol. 34, no 21, p. 9775-9785Article in journal (Refereed) Published
Abstract [en]

Aurivillius oxides have been a research focus due to their ferroelectric properties, but by replacing oxide ions by fluoride, divalent magnetic cations can be introduced, giving Bi2MO2F4(M = Fe, Co, and Ni). Our combined experimental and computational study on Bi2CoO2F4 indicates a low-temperature polar structure of P21ab symmetry (analogous to ferroelectric Bi2WO6) and a ferrimagnetic ground state. These results highlight the potential of Aurivillius oxide-fluorides for multiferroic properties. Our research has also revealed some challenges associated with the reduced tendency for polar displacements in the more ionic fluoride-based systems. 

Place, publisher, year, edition, pages
2022. Vol. 34, no 21, p. 9775-9785
Keywords [en]
Cobalt compounds, Ferrimagnetism, Ferroelectricity, Fluorine compounds, Ground state, Temperature, Tungsten compounds, Aurivillius, Co and Ni, Computational studies, Divalents, Ferrimagnetics, Ferroelectric property, Lows-temperatures, Oxide ions, Oxide-fluoride, Research focus, Bismuth compounds
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Physical Sciences
Identifiers
URN: urn:nbn:se:su:diva-211744DOI: 10.1021/acs.chemmater.2c02745ISI: 000875638300001Scopus ID: 2-s2.0-85140315505OAI: oai:DiVA.org:su-211744DiVA, id: diva2:1713588
Available from: 2022-11-25 Created: 2022-11-25 Last updated: 2022-11-25Bibliographically approved

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Mitoudi Vagourdi, EleniJohnsson, Mats

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