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Inclusion complexes of cryptophane–E with dichloromethane and chloroform: A thermodynamic and kinetic study using the 1D-EXSY NMR method
Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för fysikalisk kemi, oorganisk kemi och strukturkemi.
Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för fysikalisk kemi, oorganisk kemi och strukturkemi.
Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för fysikalisk kemi, oorganisk kemi och strukturkemi.
2008 (engelsk)Inngår i: Magnetic Resonance in Chemistry, ISSN 0749-1581, E-ISSN 1097-458X, Vol. 46, nr 12, s. 1135-1140Artikkel i tidsskrift (Fagfellevurdert) Published
Abstract [en]

Complexation equilibria and kinetics of exchange of chloroform and dichloromethane molecules between the cavity of cryptophane-E and bulk solution were investigated using NMR methods. Using one dimensional magnetization transfer (1D-EXSY type sequence), chemical exchange rates were measured in different temperature ranges, limited by the equilibrium constant values of the complexes and the boiling points of the guest substances. From the kinetic data, activation energies were calculated using the Arrhenius equation. From the temperature dependence of the association constant data, the enthalpy and entropy of complexation were estimated and compared with values for similar complexes of other cryptophanes.

sted, utgiver, år, opplag, sider
2008. Vol. 46, nr 12, s. 1135-1140
Emneord [en]
proton NMR, inclusion complexes, complexation kinetics, complexation thermodynamics
HSV kategori
Forskningsprogram
fysikalisk kemi
Identifikatorer
URN: urn:nbn:se:su:diva-15164DOI: 10.1002/mrc.2327ISI: 000261163000007OAI: oai:DiVA.org:su-15164DiVA, id: diva2:181684
Tilgjengelig fra: 2008-11-23 Laget: 2008-11-23 Sist oppdatert: 2017-12-13bibliografisk kontrollert
Inngår i avhandling
1. Chloromethane Complexation by Cryptophanes: Host-Guest Chemistry Investigated by NMR and Quantum Chemical Calculations
Åpne denne publikasjonen i ny fane eller vindu >>Chloromethane Complexation by Cryptophanes: Host-Guest Chemistry Investigated by NMR and Quantum Chemical Calculations
2012 (engelsk)Doktoravhandling, med artikler (Annet vitenskapelig)
Abstract [en]

Host–guest complexes are widely investigated because of their importance in many industrial applications. The investigation of their physico–chemical properties helps understanding the inclusion phenomenon. The hosts investigated in this work are cryptophane molecules possessing a hydrophobic cavity. They can encapsulate small organic guests such as halo–methanes (CH2Cl2, CHCl3). The encapsulation process was investigated from both the guest and the host point of view. With the help of Nuclear Magnetic Resonance (NMR), the kinetics of complex formation was determined. The information was further used to obtain the activation energies of the processes. Having done this on five different cryptophanes, it is possible to relate the energies to structural differences between the hosts. Via the dipolar interaction between the guest’s and host’s protons, one can get information on the orientation of the guest inside the cavity. Moreover, the dynamics of the guest can be further investigated by its relaxation properties. This revealed restricted motion of the guest inside the host cavity. Not only the nature of the guest plays an important role. The host is also changing its properties upon encapsulation. All the cryptophanes investigated here can exchange rapidly between many conformers. These conformers have different–sized cavities. Quantum chemical optimization of the structure of the conformers makes volume estimation possible. Not only the cavity volumes, but also the quantum-chemically obtained energies and the calculated chemical shifts of the carbon–13 atoms can be helpful to follow the changes of the host upon complex formation. The host cannot be considered as a rigid entity. Analysis of variable temperature proton and carbon-13 spectra shows that the encapsulation can be considered as a mixture of conformational selection and induced fit. The structures of the formed complexes are further investigated by means of two-dimensional nuclear Overhauser spectroscopy (NOESY). The complex formation, its kinetics and thermodynamics are found to be a complicated function of structure elements of the host, the cavity size and the guest size and properties.

sted, utgiver, år, opplag, sider
Stockholm: Department of Materials and Environmental Chemistry (MMK), Stockholm University, 2012. s. 57
Emneord
Host–guest complexes, inclusion phenomenon, cryptophanes, NMR, kinetics, activation energy, dipolar interaction, exchange, quantum chemical optimization, calculated chemical shifts, NOESY, cavity size
HSV kategori
Forskningsprogram
fysikalisk kemi
Identifikatorer
urn:nbn:se:su:diva-81472 (URN)978-91-7447-598-2 (ISBN)
Disputas
2012-11-30, Magnélisalen, Kemiska övningslaboratoriet, Svante Arrhenius väg 16 B, Stockholm, 13:00 (engelsk)
Opponent
Veileder
Merknad

At the time of the doctoral defense, the following papers were unpublished and had a status as follows: Paper 4: Accepted. Paper 5: Manuscript.

 

Tilgjengelig fra: 2012-11-08 Laget: 2012-10-22 Sist oppdatert: 2013-08-23bibliografisk kontrollert

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