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A multi-platform approach for the comprehensive analysis of per- and polyfluoroalkyl substances (PFAS) and fluorine mass balance in commercial ski wax products
Stockholm University, Faculty of Science, Department of Environmental Science.ORCID iD: 0000-0003-3042-187x
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Number of Authors: 102024 (English)In: Analytica Chimica Acta, ISSN 0003-2670, E-ISSN 1873-4324, Vol. 1314, article id 342754Article in journal (Refereed) Published
Abstract [en]

The unique properties of per- and polyfluoroalkyl substances (PFAS) have led to their extensive use in consumer products, including ski wax. Based on the risks associated with PFAS, and to align with PFAS regulations, the international ski federation (FIS) implemented a ban on products containing “C8 fluorocarbons/perfluorooctanoate (PFOA)” at all FIS events from the 2021/2022 season, leading manufactures to shift their formulations towards short-chain PFAS chemistries. To date, most studies characterising PFAS in ski waxes have measured a suite of individual substances using targeted analytical approaches. However, the fraction of total fluorine (TF) in the wax accounted for by these substances remains unclear. In this study, we sought to address this question by applying a multi-platform, fluorine mass balance approach to a total of 10 commercially available ski wax products. Analysis of TF by combustion ion chromatography (CIC) revealed concentrations of 1040–51700 μg F g−1 for the different fluorinated waxes. In comparison, extractable organic fluorine (EOF) determined in methanol extracts by CIC (and later confirmed by inductively-coupled plasma-mass spectrometry and 19F- nuclear magnetic resonance spectroscopy) ranged from 92 to 3160 μg g−1, accounting for only 3–8.8 % of total fluorine (TF). Further characterisation of extracts by cyclic ion mobility-mass spectrometry (IMS) revealed 15 individual PFAS with perfluoroalkyl carboxylic acid concentrations up to 33 μg F g−1, and 3 products exceeding the regulatory limit for PFOA (0.025 μg g−1) by a factor of up to 100. The sum of all PFAS accounted for only 0.01–1.0 % of EOF, implying a high percentage of unidentified PFAS, thus, pyrolysis gas chromatography-mass spectrometry was used to provide evidence of the nature of the non-extractable fluorine present in the ski wax products.

Place, publisher, year, edition, pages
2024. Vol. 1314, article id 342754
Keywords [en]
19F NMR, CIC, Fluorine mass balance, ICP-MS, Pyrolysis-GC-MS, Target PFAS
National Category
Environmental Sciences
Identifiers
URN: urn:nbn:se:su:diva-235594DOI: 10.1016/j.aca.2024.342754ISI: 001255401300001PubMedID: 38876512Scopus ID: 2-s2.0-85194895736OAI: oai:DiVA.org:su-235594DiVA, id: diva2:1913648
Available from: 2024-11-15 Created: 2024-11-15 Last updated: 2024-11-15Bibliographically approved

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Plassmann, MerleBenskin, Jonathan P.

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