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2006 (English)In: Inorganic Chemistry Communications, ISSN 1387-7003, E-ISSN 1879-0259, Vol. 9, no 12, p. 1195-1198Article in journal (Refereed) Published
Abstract [en]
A new μ-phenoxy-μ-metoxy di-manganese(III) complex with the trisphenolic ligand, 2,6-bis[((2-hydroxybenzyl)(2-pyridylmethyl)amino)methyl]-4-methylphenol, was isolated as a perchlorate salt. The X-ray structure shows that the two manganese(III) ions are in a distorted octrahedral enviroment with approximately perpendicular Jahn–Teller axes. Investigation of the molar magnetic susceptibility reveals a ferromagnetic coupling between the two high-spin manganese(III) ions. Fitting of the data led to g = 2 and J = 12.5 cm−1
Keywords
Manganese complex, X-ray structure, Magnetic properties
National Category
Inorganic Chemistry
Identifiers
urn:nbn:se:su:diva-23607 (URN)10.1016/j.inoche.2006.07.025 (DOI)
2005-02-242005-02-242022-02-25Bibliographically approved