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Asymmetric transfer hydrogenation of ketones catalyzed by rhodium complexes containing amino acid triazole ligands
Stockholm University, Faculty of Science, Department of Organic Chemistry.ORCID iD: 0000-0003-1271-4601
Stockholm University, Faculty of Science, Department of Organic Chemistry.ORCID iD: 0000-0001-5887-4630
2010 (English)In: Organic and biomolecular chemistry, ISSN 1477-0520, E-ISSN 1477-0539, Vol. 8, no 20, p. 4536-4539Article in journal (Refereed) Published
Abstract [en]

Active and selective catalysts for the asymmetric reduction of ketones, under transfer hydrogenation conditions, were obtained by combining [RhCl2Cp*](2), with a series of L-amino acid thioamide ligands functionalized with 1,2,3-triazoles. The obtained secondary alcohol products were formed with up to 93% ee.

Place, publisher, year, edition, pages
Royal Society of Chemistry , 2010. Vol. 8, no 20, p. 4536-4539
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Chemical Sciences
Identifiers
URN: urn:nbn:se:su:diva-49133DOI: 10.1039/c0ob00400fISI: 000282315900009OAI: oai:DiVA.org:su-49133DiVA, id: diva2:376387
Funder
Swedish Research CouncilKnut and Alice Wallenberg Foundation
Note
authorCount :2Available from: 2010-12-10 Created: 2010-12-10 Last updated: 2022-02-24Bibliographically approved

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Tinnis, FredrikAdolfsson, Hans

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