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Heterogenized Wilkinson's Catalyst for Transfer Hydrogenation of Carbonyl Compounds
Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för organisk kemi.
Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för organisk kemi.
Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för material- och miljökemi (MMK).
Vise andre og tillknytning
2011 (engelsk)Inngår i: European Journal of Organic Chemistry, ISSN 1434-193X, E-ISSN 1099-0690, nr 23, s. 4409-4414Artikkel i tidsskrift (Fagfellevurdert) Published
Abstract [en]

Wilkinson’s catalyst [RhCl(PPh3)3] was heterogenized on common silica by the use of a grafting/anchoring technique. The immobilized catalyst showed high activity and selectivity in transfer hydrogenation reactions of a range of carbonyl compounds in 2-propanol. Reactions carried out in 2-propanol at reflux afforded the corresponding alcohols in high yields in short reaction times. The heterogeneous feature ofthe catalyst allows for easy recovery and efficient reuse in the same reaction up to 5 times without any detectible loss of catalytic activity.

sted, utgiver, år, opplag, sider
Wiley-VCH Verlag GmbH 3690 & Co. KGaA, Weinheim , 2011. nr 23, s. 4409-4414
Emneord [en]
Wilkinsons’s catalyst, immobilization, heterogeneous catalysis, transfer hydrogenation, carbonyl compounds
HSV kategori
Identifikatorer
URN: urn:nbn:se:su:diva-64552DOI: 10.1002/ejoc.201100339ISI: 000294347500017OAI: oai:DiVA.org:su-64552DiVA, id: diva2:458206
Forskningsfinansiär
Knut and Alice Wallenberg Foundation
Merknad
authorCount :5Tilgjengelig fra: 2011-11-22 Laget: 2011-11-22 Sist oppdatert: 2017-12-08bibliografisk kontrollert

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