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Palladium- and Nickel-Catalyzed Alkenylation of Enolates
Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för organisk kemi.
Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för organisk kemi.
2013 (engelsk)Inngår i: Chemistry - A European Journal, ISSN 0947-6539, E-ISSN 1521-3765, Vol. 19, nr 6, s. 1858-1871Artikkel, forskningsoversikt (Fagfellevurdert) Published
Abstract [en]

Transition-metal-catalyzed alkenylation of enolates provides a direct method to synthesize broadly useful ,-unsaturated carbonyl compounds from the corresponding carbonyl compound and alkenyl halides. Despite being reported in the early seventies, this reaction class saw little development for many years. In the past decade, however, efforts to develop this reaction further have increased considerably, and many research groups have reported efficient coupling protocols, including enantioselective versions. These reactions most commonly employ palladium catalysts, but there are also some important reports using nickel. There are many examples of this powerful transformation being used in the synthesis of complex natural products.

sted, utgiver, år, opplag, sider
2013. Vol. 19, nr 6, s. 1858-1871
Emneord [en]
catalysis, CC coupling, enantioselectivity, enolates, natural products, nickel, palladium
HSV kategori
Identifikatorer
URN: urn:nbn:se:su:diva-88268DOI: 10.1002/chem.201202798ISI: 000314217100001OAI: oai:DiVA.org:su-88268DiVA, id: diva2:610815
Forskningsfinansiär
Swedish Research Council
Merknad

AuthorCount:3;

Tilgjengelig fra: 2013-03-13 Laget: 2013-03-12 Sist oppdatert: 2017-12-06bibliografisk kontrollert

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