Ändra sökning
RefereraExporteraLänk till posten
Permanent länk

Direktlänk
Referera
Referensformat
  • apa
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Annat format
Fler format
Språk
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Annat språk
Fler språk
Utmatningsformat
  • html
  • text
  • asciidoc
  • rtf
A synthesis of parameters related to the binding of neutral organic compounds to charcoal
Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för tillämpad miljövetenskap (ITM). Norwegian Geotechnical Institute (NGI), Norway; Norwegian University of Life Sciences, Norway.
Antal upphovsmän: 42016 (Engelska)Ingår i: Chemosphere, ISSN 0045-6535, E-ISSN 1879-1298, Vol. 144, s. 65-74Artikel, forskningsöversikt (Refereegranskat) Published
Abstract [en]

The sorption strength of neutral organic compounds to charcoal, also called biochar was reviewed and related to charcoal and compound properties. From 29 studies, 507 individual Freundlich sorption.coefficients were compiled that covered the sorption strength of 107 organic contaminants. These sorption coefficients were converted into charcoal-water distribution coefficients (K-D) at aqueous concentrations of 1 ng/L, 1 mu g/L and 1 mg/L. Reported log K-D values at 1 mu g/L varied from 0.38 to 8.25 across all data. Variation was also observed within the compound classes; pesticides, herbicides and insecticides, PAHs, phthalates, halogenated organics, small organics, alcohols and PCBs. Five commonly reported variables; charcoal production temperature T, surface area SA, H/C and 0/C ratios and organic compound octanolwater partitioning coefficient, were correlated with K-D values using single and multiple-parameter linear regressions. The sorption strength of organic compounds to charcoals increased with increasing charcoal production temperature T, charcoal SA and organic pollutant octanol-water partitioning coefficient and decreased with increasing charcoal O/C ratio and charcoal H/C ratio. T was found to be correlated with SA (r(2) = 0.66) and O/C (r(2) = 0.50), particularly for charcoals produced from wood feedstocks (r2 = 0.73 and 0.80, respectively). The resulting regression: log K-D = (0.18 +/- 0.06) log K-ow + (5.74 +/- 1.40) log T + (0.85 +/- 0.15) log SA + (1.60 +/- 0.29) log OC + (-0.89 +/- 0.20) log HC + (-13.20 +/- 3.69), r(2) = 0.60, root mean squared error = 0.95, n = 151 was obtained for all variables. This information can be used as an initial screening to identify charcoals for contaminated soil and sediment remediation.

Ort, förlag, år, upplaga, sidor
2016. Vol. 144, s. 65-74
Nyckelord [en]
Charcoal, Biochar, Sorption, Surface area, Temperature, Hydrophobicity, Elemental composition
Nationell ämneskategori
Geovetenskap och miljövetenskap
Identifikatorer
URN: urn:nbn:se:su:diva-126876DOI: 10.1016/j.chemosphere.2015.08.047ISI: 000367774400010PubMedID: 26347927OAI: oai:DiVA.org:su-126876DiVA, id: diva2:905448
Tillgänglig från: 2016-02-22 Skapad: 2016-02-16 Senast uppdaterad: 2022-02-23Bibliografiskt granskad

Open Access i DiVA

Fulltext saknas i DiVA

Övriga länkar

Förlagets fulltextPubMed

Person

Cornelissen, Gerard

Sök vidare i DiVA

Av författaren/redaktören
Cornelissen, Gerard
Av organisationen
Institutionen för tillämpad miljövetenskap (ITM)
I samma tidskrift
Chemosphere
Geovetenskap och miljövetenskap

Sök vidare utanför DiVA

GoogleGoogle Scholar

doi
pubmed
urn-nbn

Altmetricpoäng

doi
pubmed
urn-nbn
Totalt: 47 träffar
RefereraExporteraLänk till posten
Permanent länk

Direktlänk
Referera
Referensformat
  • apa
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Annat format
Fler format
Språk
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Annat språk
Fler språk
Utmatningsformat
  • html
  • text
  • asciidoc
  • rtf