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Catalyst-solvent interactions in a dinuclear Ru-based water oxidation catalyst
Stockholm University, Faculty of Science, Department of Organic Chemistry.
Stockholm University, Faculty of Science, Department of Organic Chemistry. Nuclear Materials Authority, Egypt.
Stockholm University, Faculty of Science, Department of Organic Chemistry.
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2016 (English)In: Dalton Transactions, ISSN 1477-9226, E-ISSN 1477-9234, Vol. 45, no 47, 19024-19033 p.Article in journal (Refereed) Published
Abstract [en]

Photocatalytic water oxidation represents a key process in conversion of solar energy into fuels and can be facilitated by the use of molecular transition metal-based catalysts. A novel straightforward approach for covalent linking of the catalytic units to other moieties is demonstrated by preparation of a dinuclear complex containing two [Ru(pdc)(pic)(3)]-derived units (pdc = 2,6-pyridinedicarboxylate, pic = 4-picoline). The activity of this complex towards chemical and photochemical oxidation of water was evaluated and a detailed insight is given into the interactions between the catalyst and acetonitrile, a common co-solvent employed to increase solubility of water oxidation catalysts. The solvent-induced transformations were studied by electrochemical and spectroscopic techniques and the relevant quantitative parameters were extracted.

Place, publisher, year, edition, pages
Royal Society of Chemistry, 2016. Vol. 45, no 47, 19024-19033 p.
National Category
Chemical Sciences
Identifiers
URN: urn:nbn:se:su:diva-139388DOI: 10.1039/c6dt03789eISI: 000390082900029PubMedID: 27853776OAI: oai:DiVA.org:su-139388DiVA: diva2:1072221
Funder
Swedish Research CouncilKnut and Alice Wallenberg FoundationCarl Tryggers foundation
Available from: 2017-02-07 Created: 2017-02-06 Last updated: 2017-05-27Bibliographically approved

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Shatskiy, AndreyAbdel-Magied, Ahmed F.Rabten, WangchukLaine, Tanja M.Sun, JunliangAndersson, Pher G.Kärkäs, Markus D.Johnston, Eric V.Åkermark, Bjorn
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