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A redox-economical synthesis of trifluoromethylated enamides with the Langlois reagent
Stockholm University, Faculty of Science, Department of Organic Chemistry.ORCID iD: 0000-0002-8977-4963
Stockholm University, Faculty of Science, Department of Organic Chemistry.ORCID iD: 0000-0002-9085-0476
2017 (English)In: Organic and biomolecular chemistry, ISSN 1477-0520, E-ISSN 1477-0539, Vol. 15, no 8, 1771-1775 p.Article in journal (Refereed) Published
Abstract [en]

A redox-economical strategy for the synthesis of trifluoromethylated enamides using copper catalysis is reported. The reaction employs the inexpensive Langlois reagent (CF3SO2Na) and takes place without the need of an external oxidant. The trifluoromethylated enamide products can easily be converted into the corresponding ketone, saturated amide or oxazole.

Place, publisher, year, edition, pages
2017. Vol. 15, no 8, 1771-1775 p.
National Category
Organic Chemistry
Research subject
Organic Chemistry
Identifiers
URN: urn:nbn:se:su:diva-140135DOI: 10.1039/C7OB00203CISI: 000395884000005OAI: oai:DiVA.org:su-140135DiVA: diva2:1077708
Funder
Wenner-Gren Foundations
Available from: 2017-02-28 Created: 2017-02-28 Last updated: 2017-04-03Bibliographically approved

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Yang, Hai-BinSelander, Nicklas
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