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Synthesis of trifluoromethyl moieties by late-stage copper (I) mediated nucleophilic fluorination
Stockholm University, Faculty of Science, Department of Organic Chemistry. Karolinska Intitutet, Sweden.
Stockholm University, Faculty of Science, Department of Organic Chemistry. Karolinska Intitutet, Sweden.
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Number of Authors: 6
2017 (English)In: Journal of fluorine chemistry, ISSN 0022-1139, E-ISSN 1873-3328, Vol. 194, 51-57 p.Article in journal (Refereed) Published
Abstract [en]

The nucleophilic fluorination of bromodifluoromethyl derivatives mediated by the complex (PPh3)(3)CuF is described. Under the reaction conditions, different trifluoroacetates, trifluorolcetones, trifluoroarenes and trifluoroacetamides were obtained in good yields.

Place, publisher, year, edition, pages
2017. Vol. 194, 51-57 p.
Keyword [en]
Nucleophilic fluorination, Copper, Trifluoroacetate, Trifluoromethylarene, Trifluoroacetamide
National Category
Chemical Sciences
Identifiers
URN: urn:nbn:se:su:diva-141365DOI: 10.1016/j.jfluchem.2016.12.017ISI: 000393938200007OAI: oai:DiVA.org:su-141365DiVA: diva2:1092304
Available from: 2017-05-02 Created: 2017-05-02 Last updated: 2017-05-02Bibliographically approved

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Cortés González, Miguel A.Lübcke, MarvinSzabó, Kálmán J.
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