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Synthesis and crystal structure of three new bismuth(III) arylsulfonatocarboxylates
Stockholm University, Faculty of Science, Department of Materials and Environmental Chemistry (MMK).
Number of Authors: 3
2017 (English)In: Zeitschrift für Kristallographie - Crystalline Materials, ISSN 2194-4946, Vol. 232, no 1-3, 245-253 p.Article in journal (Refereed) Published
Abstract [en]

Three new bismuth arylsulfonatocarboxylates [Bi(OH)(SB)] (1), [Bi-4(ST)(2)(HST)O-2(H2O)(2)]center dot H2O (2) and [Bi-4(ST)(2)O-3(H2O)(2)] (3) were synthesized under solvothermal reaction conditions at 180 degrees C using the potassium or sodium salt of 4-sulfobenzoic acid (H2SB) and 2-sulfoterephthalic acid (H3ST), respectively. The compounds were characterized in detail and the crystal structures were determined from single crystal X-ray diffraction data. Phase purity was confirmed by powder X-ray diffraction and elemental analysis. Structural comparisons to the only three other known bismuth sulfonatocarboxylates are presented. Due to the higher reaction temperatures employed for the synthesis of the title compounds a higher degree of condensation of the BiOx polyhedra (X = 7 or 8) to tetrameric units, 1D chains or a 2D layer is observed. Connection through the organic linker molecules leads to the formation of 3D coordination polymers in all three title compounds.

Place, publisher, year, edition, pages
2017. Vol. 232, no 1-3, 245-253 p.
Keyword [en]
bismuth, coordination polymer, sulfonatocarboxylates
National Category
Chemical Sciences
Identifiers
URN: urn:nbn:se:su:diva-142557DOI: 10.1515/zkri-2016-1980ISI: 000394243800019OAI: oai:DiVA.org:su-142557DiVA: diva2:1092700
Available from: 2017-05-03 Created: 2017-05-03 Last updated: 2017-05-03Bibliographically approved

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Inge, Andrew Kentaro
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