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Chirally sensitive collision induced dissociation of proton-bound diastereomeric complexes of tryptophan and 2-butanol
Stockholm University, Faculty of Science, Department of Physics.
Stockholm University, Faculty of Science, Department of Physics.
Stockholm University, Faculty of Science, Department of Physics.
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Number of Authors: 6
2017 (English)In: Chirality, ISSN 0899-0042, E-ISSN 1520-636X, Vol. 29, no 3-4, p. 115-119Article in journal (Refereed) Published
Abstract [en]

In this work we report the stereo-dependent collision-induced dissociation (CID) of proton-bound complexes of tryptophan and 2-butanol. The dissociation efficiency was measured as a function of collision energy in single collision mode. The homochiral complex was found to be less stable against CID than a heterochiral one. Additional gas dependence measurements were performed with diastereomeric complexes that confirm the findings.

Place, publisher, year, edition, pages
2017. Vol. 29, no 3-4, p. 115-119
Keyword [en]
amino acids, chiral recognition, collision induced dissociation, gas phase, mass spectrometry
National Category
Chemical Sciences Medicinal Chemistry
Identifiers
URN: urn:nbn:se:su:diva-143477DOI: 10.1002/chir.22679ISI: 000399696300002PubMedID: 28332282OAI: oai:DiVA.org:su-143477DiVA, id: diva2:1104073
Available from: 2017-05-31 Created: 2017-05-31 Last updated: 2018-01-13Bibliographically approved

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Rebrov, OleksiiKulyk, KostiantynThomas, Richard D.Larsson, Mats
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