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Rich Coordination Chemistry of pi-Acceptor Dibenzoarsole Ligands
Stockholm University, Faculty of Science, Department of Organic Chemistry.
Number of Authors: 3
2017 (English)In: Inorganic Chemistry, ISSN 0020-1669, E-ISSN 1520-510X, Vol. 56, no 8, p. 4504-4511Article in journal (Refereed) Published
Abstract [en]

A series of dibenzoarsole (also known as 9-arsafluorene) derivatives have been prepared, and their coordination chemistry has been investigated. The different ligand topology and the arsenic substituents govern the reactivity of the ligands. We report various crystal structures of palladium and platinum complexes derived from this family of ligands. The biphenyl backbone of the bridged bidentate ligands allows very flexible coordination. We have also studied the application of an allylic Pd complex in nucleophilic substitution reactions, revealing that the benzoarsole substituent is susceptible to metal insertion.

Place, publisher, year, edition, pages
2017. Vol. 56, no 8, p. 4504-4511
National Category
Organic Chemistry
Identifiers
URN: urn:nbn:se:su:diva-143581DOI: 10.1021/acs.inorgchem.7b00100ISI: 000399625600030PubMedID: 28345894OAI: oai:DiVA.org:su-143581DiVA, id: diva2:1104363
Available from: 2017-06-01 Created: 2017-06-01 Last updated: 2017-06-01Bibliographically approved

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