Change search
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf
Hydrothermal Synthesis of the Oxofluoride FeSbO2F2-An Anti-ferromagnetic Spin S=5/2 Compound
Stockholm University, Faculty of Science, Department of Materials and Environmental Chemistry (MMK).
Stockholm University, Faculty of Science, Department of Materials and Environmental Chemistry (MMK).
Number of Authors: 3
2017 (English)In: Inorganic Chemistry, ISSN 0020-1669, E-ISSN 1520-510X, Vol. 56, no 8, 4662-4667 p.Article in journal (Refereed) Published
Abstract [en]

The new oxofluoride compound FeSbO2F2 was synthesized by hydro thermal techniques at 230 degrees C. Its crystal structure was determined from single-crystal Xray diffraction data. The compound crystallizes in the monoclinic space group C2/c with one crystallographic site for Fe3+ and SP3+, respectively. The crystal structure is made of [FeO2F4] octahedra and seesaw [SbO4] building blocks. These are connected to form [FeO2F2] layers and [SbO2] chains that bond together via the oxygen atoms to form the three-dimensional framework structure. Magnetic susceptibility and heat capacity measurements indicate long-range anti-ferromagnetic ordering below a Neel temperature of similar to 175 K Two-dimensional anti-ferromagnetic short-range order in the square planar net of the Fe3+ cations extends to temperatures far above the Neel temperature.

Place, publisher, year, edition, pages
2017. Vol. 56, no 8, 4662-4667 p.
National Category
Chemical Sciences
Identifiers
URN: urn:nbn:se:su:diva-143582DOI: 10.1021/acs.inorgchem.7b00301ISI: 000399625600047OAI: oai:DiVA.org:su-143582DiVA: diva2:1104366
Available from: 2017-06-01 Created: 2017-06-01 Last updated: 2017-06-01Bibliographically approved

Open Access in DiVA

No full text

Other links

Publisher's full text

Search in DiVA

By author/editor
Johnsson, Mats
By organisation
Department of Materials and Environmental Chemistry (MMK)
In the same journal
Inorganic Chemistry
Chemical Sciences

Search outside of DiVA

GoogleGoogle Scholar

Altmetric score

Total: 42 hits
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf