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N-Trifluoromethylation of Nitrosoarenes with Sodium Triflinate
Stockholm University, Faculty of Science, Department of Organic Chemistry.
Stockholm University, Faculty of Science, Department of Organic Chemistry.
Stockholm University, Faculty of Science, Department of Organic Chemistry.
Number of Authors: 3
2017 (English)In: Organic Letters, ISSN 1523-7060, E-ISSN 1523-7052, Vol. 19, no 9, 2374-2377 p.Article in journal, Letter (Refereed) Published
Abstract [en]

A highly efficient N-trifluoromethylation of nitro-soarenes is reported. The inexpensive and convenient Langlois reagent (sodium triflinate) is employed as a Ch(3)-radical source in combination with a copper catalyst and an oxidant. N-Trifluoromethylated hychoxylamines are obtained in high yields within 1 h at room temperature. The addition of hydroquinone was found to be instrumental to prevent the formation of side products. The method is high-yielding is scalable, and displays a high functional group tolerance.

Place, publisher, year, edition, pages
2017. Vol. 19, no 9, 2374-2377 p.
National Category
Chemical Sciences
Identifiers
URN: urn:nbn:se:su:diva-144846DOI: 10.1021/acs.orglett.7b00908ISI: 000401044500045PubMedID: 28402669OAI: oai:DiVA.org:su-144846DiVA: diva2:1119402
Available from: 2017-07-04 Created: 2017-07-04 Last updated: 2017-07-04Bibliographically approved

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van der Werf, AngelaHribersek, MaticSelander, Nicklas
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