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Ultrafast Independent N-H and N-C Bond Deformation Investigated with Resonant Inelastic X-Ray Scattering
Stockholm University, Faculty of Science, Department of Physics.
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Number of Authors: 17
2017 (English)In: Angewandte Chemie International Edition, ISSN 1433-7851, E-ISSN 1521-3773, Vol. 56, no 22, 6088-6092 p.Article in journal (Refereed) Published
Abstract [en]

The femtosecond excited-state dynamics following resonant photoexcitation enable the selective deformation of N-H and N-C chemical bonds in 2-thiopyridone in aqueous solution with optical or X-ray pulses. In combination with multiconfigurational quantum-chemical calculations, the orbital-specific electronic structure and its ultrafast dynamics accessed with resonant inelastic X-ray scattering at the N 1s level using synchrotron radiation and the soft X-ray free-electron laser LCLS provide direct evidence for this controlled photoinduced molecular deformation and its ultrashort time-scale.

Place, publisher, year, edition, pages
2017. Vol. 56, no 22, 6088-6092 p.
Keyword [en]
nitrogen, photochemistry, protonation, RIXS (resonant inelastic X-ray scattering), selective bond cleavage
National Category
Chemical Sciences
Identifiers
URN: urn:nbn:se:su:diva-144820DOI: 10.1002/anie.201700239ISI: 000401326300011PubMedID: 28374523OAI: oai:DiVA.org:su-144820DiVA: diva2:1121530
Available from: 2017-07-11 Created: 2017-07-11 Last updated: 2017-07-11Bibliographically approved

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