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From clusters to condensed phase - FT IR studies of water
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Number of Authors: 72017 (English)In: Journal of Molecular Liquids, ISSN 0167-7322, E-ISSN 1873-3166, Vol. 235, p. 7-10Article in journal (Refereed) Published
Abstract [en]

Intermolecular hydrogen bonding, which is formed between water molecules in the condensed state, causes a variety of unique properties of liquid water. In this paper the results of experimental FT IR studies of water trapped in an Ar matrix as well as condensed water at temperatures from 133 to 293 K are presented. It is shown that the temperature evolution of the FTIR-spectra of water trapped in low-temperature matrices can be considered as an experimental model of the structure transformation of water during the phase transition from gas phase to condensed confined water. The comparison of the vibrational spectra of water in matrix isolation with the corresponding spectra of condensed water gives information about the peculiarities of H-bonded structures of water.

Place, publisher, year, edition, pages
2017. Vol. 235, p. 7-10
Keywords [en]
Water, Cluster, FTIR, Matrix isolation, Hydrogen bond
National Category
Physical Sciences
Identifiers
URN: urn:nbn:se:su:diva-144675DOI: 10.1016/j.molliq.2016.12.037ISI: 000402358300002Scopus ID: 2-s2.0-85010638043OAI: oai:DiVA.org:su-144675DiVA, id: diva2:1128212
Conference
7th Conference of the Physics of Liquid Matter - Modern Problems (PLMMP), Kyiv, Ukraine, May 27-30, 2016
Available from: 2017-07-24 Created: 2017-07-24 Last updated: 2022-10-19Bibliographically approved

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Pettersson, Lars G. M.

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