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Highly Selective Olefin-Assisted Pd-II-Catalyzed Oxidative Alkynylation of Enallenes
Stockholm University, Faculty of Science, Department of Organic Chemistry.
Stockholm University, Faculty of Science, Department of Organic Chemistry.
Stockholm University, Faculty of Science, Department of Organic Chemistry.
Stockholm University, Faculty of Science, Department of Organic Chemistry.
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2017 (English)In: Chemistry - A European Journal, ISSN 0947-6539, E-ISSN 1521-3765, Vol. 23, no 33, p. 7896-7899Article in journal (Refereed) Published
Abstract [en]

An olefin-assisted, palladium-catalyzed oxidative alkynylation of enallenes for regio- and stereoselective synthesis of substituted trienynes has been developed. The reaction shows a broad substrate scope and good tolerance for various functional groups on the allene moiety, including carboxylic acid esters, free hydroxyls, imides, and alkyl groups. Also, a wide range of terminal alkynes with electron-donating and electron-withdrawing aryls, heteroaryls, alkyls, trimethylsilyl, and free hydroxyl groups are tolerated.

Place, publisher, year, edition, pages
Wiley-VCH Verlagsgesellschaft, 2017. Vol. 23, no 33, p. 7896-7899
Keywords [en]
alkynylation, enallene, olefin-assisted, oxidation, palladium
National Category
Organic Chemistry
Identifiers
URN: urn:nbn:se:su:diva-145317DOI: 10.1002/chem.201701654ISI: 000403150100011PubMedID: 28440882OAI: oai:DiVA.org:su-145317DiVA, id: diva2:1128412
Funder
Swedish Research CouncilBerzelii Centre EXSELENTKnut and Alice Wallenberg FoundationAvailable from: 2017-07-25 Created: 2017-07-25 Last updated: 2019-02-15Bibliographically approved

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