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Hydrogenous Zintl Phases: Interstitial Versus Polyanionic Hydrides
Arizona State University, USA.
Arizona State University, USA.
Arizona State University, USA.
2011 (English)In: Zintl Phases: Principles and Recent Developments / [ed] Thomas F. Fässler, Springer Berlin/Heidelberg, 2011, Vol. 139, 143-161 p.Chapter in book (Refereed)
Abstract [en]

Hydrogen may be incorporated in Zintl phases in two different ways: either hydridic where H is exclusively coordinated by electropositive metals (interstitial hydrides), or as part of the polyanion where it acts as a covalently bonded ligand (polyanionic hydride). Both scenarios provide novel coordination environments and bonding scenarios for the atoms involved. This makes hydrogenous Zintl phases important model systems for fundamental studies of hydrogen–metal interactions. Simultaneously, hydrogen-induced chemical structure and physical property changes provide exciting prospects for materials science.

Place, publisher, year, edition, pages
Springer Berlin/Heidelberg, 2011. Vol. 139, 143-161 p.
Series
Structure and Bonding, ISSN 0081-5993 ; 139
Keyword [en]
Main group metal hydrides, Polar intermetallic compounds, Polyanionic hydrides, Zintl phases
National Category
Chemical Sciences
Research subject
Inorganic Chemistry
Identifiers
URN: urn:nbn:se:su:diva-146829DOI: 10.1007/430_2010_20ISBN: 978-3-642-21149-2 (print)ISBN: 978-3-642-21150-8 (electronic)OAI: oai:DiVA.org:su-146829DiVA: diva2:1140630
Available from: 2017-09-12 Created: 2017-09-12 Last updated: 2017-09-13Bibliographically approved
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Häussermann, UlrichKranak, Verina F.
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