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2,2-Diiododimedone: a mild electrophilic iodinating agent for the selective synthesis of alpha-iodoketones from allylic alcohols
Stockholm University, Faculty of Science, Department of Organic Chemistry.
Stockholm University, Faculty of Science, Department of Organic Chemistry.ORCID iD: 0000-0002-1333-7740
Stockholm University, Faculty of Science, Department of Organic Chemistry.
Stockholm University, Faculty of Science, Department of Organic Chemistry.
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2017 (English)In: Chemical Communications, ISSN 1359-7345, E-ISSN 1364-548X, Vol. 53, no 71, p. 9842-9845Article in journal (Refereed) Published
Abstract [en]

2,2-Diiodo-5,5-dimethylcyclohexane-1,3-dione is reported as a new electrophilic iodinating agent that selectively iodinates electron-rich aromatics. In contrast to other common electrophilic iodinating reagents, its mild nature allows it to be used for the selective synthesis of alpha-iodinated carbonyl compounds from allylic alcohols through a 1,3-hydrogen shift/iodination process catalyzed by iridium(III) complexes.

Place, publisher, year, edition, pages
2017. Vol. 53, no 71, p. 9842-9845
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Organic Chemistry
Research subject
Organic Chemistry
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URN: urn:nbn:se:su:diva-148095DOI: 10.1039/c7cc04823hISI: 000409481000003PubMedID: 28809976OAI: oai:DiVA.org:su-148095DiVA, id: diva2:1150798
Available from: 2017-10-20 Created: 2017-10-20 Last updated: 2018-11-01Bibliographically approved

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Martinez-Erro, SamuelBermejo Gómez, AntonioVazquez-Romero, AnaErbing, ElisMartín-Matute, Belén
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