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2,2-Diiododimedone: a mild electrophilic iodinating agent for the selective synthesis of alpha-iodoketones from allylic alcohols
Stockholm University, Faculty of Science, Department of Organic Chemistry.
Stockholm University, Faculty of Science, Department of Organic Chemistry.
Stockholm University, Faculty of Science, Department of Organic Chemistry.
Stockholm University, Faculty of Science, Department of Organic Chemistry.
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Number of Authors: 5
2017 (English)In: Chemical Communications, ISSN 1359-7345, E-ISSN 1364-548X, Vol. 53, no 71, 9842-9845 p.Article in journal (Refereed) Published
Abstract [en]

2,2-Diiodo-5,5-dimethylcyclohexane-1,3-dione is reported as a new electrophilic iodinating agent that selectively iodinates electron-rich aromatics. In contrast to other common electrophilic iodinating reagents, its mild nature allows it to be used for the selective synthesis of alpha-iodinated carbonyl compounds from allylic alcohols through a 1,3-hydrogen shift/iodination process catalyzed by iridium(III) complexes.

Place, publisher, year, edition, pages
2017. Vol. 53, no 71, 9842-9845 p.
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Chemical Sciences
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URN: urn:nbn:se:su:diva-148095DOI: 10.1039/c7cc04823hISI: 000409481000003PubMedID: 28809976OAI: oai:DiVA.org:su-148095DiVA: diva2:1150798
Available from: 2017-10-20 Created: 2017-10-20 Last updated: 2017-10-20Bibliographically approved

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Martinez-Erro, SamuelBermejo Gómez, AntonioErbing, ElisMartín-Matute, Belén
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