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Trifluoromethylthiolation-Based Bifunctionalization of Diazocarbonyl Compounds by Rhodium Catalysis
Stockholm University, Faculty of Science, Department of Organic Chemistry. Karolinska Institutet, Sweden.
Stockholm University, Faculty of Science, Department of Organic Chemistry.
Stockholm University, Faculty of Science, Department of Organic Chemistry. Karolinska Institutet, Sweden.
Number of Authors: 32017 (English)In: Organic Letters, ISSN 1523-7060, E-ISSN 1523-7052, Vol. 19, no 17, p. 4548-4551Article in journal (Refereed) Published
Abstract [en]

A new Rh-catalyzed, three-component reaction for the oxytrifluoromethylthiolation of alpha-diazoketones was developed. The SCF3 functionality was introduced using a stable dibenzenesulfonimide reagent under mild conditions. Alcohols, acetals, and ethers were used as the alkoxy sources. Cyclic ethers underwent a trifunctionalization reaction through the introduction of SCF3, OR, and N(SO2Ph)(2) substituents in a single step.

Place, publisher, year, edition, pages
2017. Vol. 19, no 17, p. 4548-4551
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Organic Chemistry
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URN: urn:nbn:se:su:diva-147888DOI: 10.1021/acs.orglett.7b02139ISI: 000409566400035PubMedID: 28816049OAI: oai:DiVA.org:su-147888DiVA, id: diva2:1151309
Available from: 2017-10-23 Created: 2017-10-23 Last updated: 2017-10-23Bibliographically approved

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