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Zn3Sb4O6F6: Hydrothermal synthesis, crystal structure and nonlinear optical properties
Stockholm University, Faculty of Science, Department of Materials and Environmental Chemistry (MMK).
Number of Authors: 4
2017 (English)In: Journal of Solid State Chemistry, ISSN 0022-4596, E-ISSN 1095-726X, Vol. 256, 158-161 p.Article in journal (Refereed) Published
Abstract [en]

Zn3Sb4O6F6 has been synthesized hydrothermally at 230 degrees C. The crystal structure was determined from single crystal X-ray diffraction data. It crystallizes in the cubic non-centrosymmetric space group I-43m with the unit cell parameter a = 8.1291(4) angstrom and is isostructural with M3Sb4O6F6 (M = Co, Ni). The new compound is the first oxofluoride containing Zn2+ and a p-element cation with a stereochemically active lone pair. The crystal structure is made up by [ZnO2F4] octahedra forming a network via corner sharing at F-atoms and [SbO3] trigonal pyramids that form [Sb4O6] cages that connect via the O-atoms to the Zn-atoms. Powder second harmonic generation (SHG) measurements using 1064 nm radiation on Zn3Sb4O6F6 indicate an SHG intensity of approximately 40 x alpha-SiO2.

Place, publisher, year, edition, pages
2017. Vol. 256, 158-161 p.
Keyword [en]
Oxofluoride, Hydrothermal synthesis, Crystal structure, SHG, Properties
National Category
Chemical Sciences
Identifiers
URN: urn:nbn:se:su:diva-148816DOI: 10.1016/j.jssc.2017.08.033ISI: 000413134600022OAI: oai:DiVA.org:su-148816DiVA: diva2:1156788
Available from: 2017-11-14 Created: 2017-11-14 Last updated: 2017-11-14Bibliographically approved

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