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Indium(III)-Catalyzed Transformations of Alkynes: Recent Advances in Carbo- and Heterocyclization Reactions
Stockholm University, Faculty of Science, Department of Organic Chemistry.ORCID iD: 0000-0002-6536-8506
Stockholm University, Faculty of Science, Department of Organic Chemistry.ORCID iD: 0000-0001-6517-8879
Stockholm University, Faculty of Science, Department of Organic Chemistry.ORCID iD: 0000-0002-9085-0476
2017 (English)In: Synthesis (Stuttgart), ISSN 0039-7881, E-ISSN 1437-210X, Vol. 49, no 22, 4931-4941 p.Article in journal (Refereed) Published
Abstract [en]

The use of a well-chosen catalyst is instrumental for the development of more efficient, economical and environmentally friendly reactions. In recent decades, indium-based catalysts have proven to be competitive and useful alternatives to transition-metal catalysts such as silver and gold. In this short review, we present some of the recent advances in indium(III)-catalyzed transformations of alkynes, with a focus on cyclization reactions. 1 Introduction 2 Terminal Alkynes as Nucleophiles 3 Nucleophilic Additions to Alkynes 4 Carbo- and Heterocyclization Reactions 4.1 Carbocyclization 4.2 Oxygen-Based Heterocycles 4.3 Nitrogen-Based Heterocycles 4.4 Sulfur-Based Heterocycles 5 Conclusion

Place, publisher, year, edition, pages
2017. Vol. 49, no 22, 4931-4941 p.
Keyword [en]
alkynes, carbocycles, catalysis, heterocycles, indium, Lewis acids
National Category
Organic Chemistry
Identifiers
URN: urn:nbn:se:su:diva-150020DOI: 10.1055/s-0036-1588555ISI: 000414660900003OAI: oai:DiVA.org:su-150020DiVA: diva2:1167619
Funder
Swedish Research Council
Available from: 2017-12-19 Created: 2017-12-19 Last updated: 2018-01-10Bibliographically approved

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Pathipati, Stalin R.van der Werf, AngelaSelander, Nicklas
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