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Palladium-Catalyzed Oxidative Borylation of Allylic C-H Bonds in Alkenes
Stockholm University, Faculty of Science, Department of Organic Chemistry.
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Number of Authors: 52017 (English)In: Organic Letters, ISSN 1523-7060, E-ISSN 1523-7052, Vol. 19, no 24, p. 6590-6593Article in journal (Refereed) Published
Abstract [en]

This communication describes an efficient palladium pincer complex-catalyzed allylic C-H borylation of alkenes. The transformation exhibits high regio- and stereo selectivity with a variety of linear alkenes. A synthetically useful feature of this allylic C-H borylation method is that all allyl-Bpin products can be isolated in usually high yields. Preliminary mechanistic studies indicate that this CH borylation reaction proceeds via Pd(IV) pincer complex intermediates.

Place, publisher, year, edition, pages
2017. Vol. 19, no 24, p. 6590-6593
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Organic Chemistry
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URN: urn:nbn:se:su:diva-150930DOI: 10.1021/acs.orglett.7b03296ISI: 000418392400033PubMedID: 29190108OAI: oai:DiVA.org:su-150930DiVA, id: diva2:1171901
Available from: 2018-01-08 Created: 2018-01-08 Last updated: 2018-01-08Bibliographically approved

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