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Intermolecular Pummerer Coupling with Carbon Nucleophiles in Non-Electrophilic Media
Stockholm University, Faculty of Science, Department of Organic Chemistry.
Stockholm University, Faculty of Science, Department of Organic Chemistry.
Stockholm University, Faculty of Science, Department of Organic Chemistry.ORCID iD: 0000-0001-9199-6736
Number of Authors: 3
2017 (English)In: Angewandte Chemie International Edition, ISSN 1433-7851, E-ISSN 1521-3773, Vol. 56, no 50, 16042-16046 p.Article in journal (Refereed) Published
Abstract [en]

A new Pummerer-type C-C coupling protocol is introduced based on turbo-organomagnesium amides, which unlike traditional Pummerer reactions, does not require strong electrophilic activators, engages a broad range of C(sp(3))-, C(sp(2))-, and C(sp)-nucleophiles, and seamlessly integrates with C-H and C-X magnesiation. Given the central character of sulfur compounds in organic chemistry, this protocol allows access to unrelated carbonyls, olefins, organometallics, halides, and boronic esters through a single strategy.

Place, publisher, year, edition, pages
2017. Vol. 56, no 50, 16042-16046 p.
Keyword [en]
C-C coupling, magnesium, main group elements, Pummerer reaction, sulfur
National Category
Chemical Sciences
Identifiers
URN: urn:nbn:se:su:diva-150977DOI: 10.1002/anie.201709715ISI: 000417200600045PubMedID: 29053208OAI: oai:DiVA.org:su-150977DiVA: diva2:1173407
Available from: 2018-01-12 Created: 2018-01-12 Last updated: 2018-01-12Bibliographically approved

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